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The unexpected but facile prepn. of the Ag salt of the least coordinating [(RO)3Al-F-Al(OR)3]- anion (R = C(CF3)3) by reaction of Ag[Al(OR)4] with one equiv. of PCl3 is described. The mechanism of the formation of Ag[(RO)3Al-F-Al(OR)3] is explained based o ...
The oxidation of organic and inorganic compounds during ozonation can occur via ozone or OH radicals or a combination thereof. The oxidation pathway is determined by the ratio of ozone and OH radical concentrations and the corresponding kinetics. A huge da ...
A compound of formula (I): (X)nRuLL1 where n is 1 or 2, preferably 2, and in which Ru is ruthenium; each X independently is selected from Cl, SCN, H2O, Br, I, CN and SeCN and L is a ligand of formulae (a) to (g) and L1 is selected from a ligand of formulae ...
(Ecole Polytechnique Federale de Lausanne (EPFL), Switz.).1994
This work reports the hydrogenation of carbon dioxide/inorganic carbonate salts to formic acid/formate in two phase systems comprising an ionic phase, in which the catalyst is immobilized, and an aqueous phase in which the carbonates and formate are confin ...
The study of intracellular communication requires devices that can not only monitor the bioelectric activity, but also control and observe the biochemical environment at the cellular level. This paper reports on the development and characterisation of impl ...
The recently developed technique of energy‐dependent electrospray ionisation mass spectrometry (EDESI‐MS) has been implemented on a triple quadrupole mass spectrometer such that fragmentation occurs in the collision cell rather than at the skimmer cone. Th ...
A compound, in metal-free or metal complex form of formula (1) to (3) in which R is hydrogen or C1-30 alkyl; X is hydrogen, halogen (preferably Cl or Br) or C1-30 alkyl. ...
(Ecole Polytechnique Federale de Lausanne (epfl), Switz.).1995
A Multicomponent Aerosol Dynamics Model (MADM) capable of solving the condensation/evaporation equation of atmospheric aerosols is presented. Condensable species may be organic and/or inorganic. For the inorganic constituents the equilibrium model ISORROPI ...