Concept
Cyclopropane
Related publications (21)
Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions
Nukorn Plainpan, Jantira Chimlert
Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Va ...
WILEY-V C H VERLAG GMBH2023Unified divergent strategy towards the total synthesis of the three sub-classes of hasubanan alkaloids
Qian Wang, Jieping Zhu, Guang Li
Elegant asymmetric synthesis of hasubanan alkaloids have been developed over the past decades. However, a divergent approach leading to all three sub-classes of this family of natural products remains unknown. We report herein the realization of such an en ...
2021Azide Radical Initiated Ring Opening of Cyclopropenes Leading to Alkenyl Nitriles and Polycyclic Aromatic Compounds
Jérôme Waser, Bastian Antoine Rodolphe Claude Muriel
We report herein a radical‐mediated amination of cyclopropenes. The transformation proceeds through a cleavage of the three‐membered ring after the addition of an azide radical on the strained double bond and leads to tetrasubstituted alkenyl nitrile deriv ...
2020Strain-Promoted C-C Bond Cleavages of Cyclobutanes
Laetitia Marie Mélanie Souillart
The catalytic activation of carbon-carbon single bonds is a major challenge in organometallic chemistry, since the lack of prefunctionalization steps opens the way to new, economically and ecologically attractive reaction pathways. Strained ring substrates ...
EPFL2015