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Catalytic supercritical water gasification of isopropanol (450 degrees C, 30 MPa) over Ru/C catalysts was carried out in a fixed-bed plug flow reactor. In the absence of Ru, isopropanol decomposed to solid carbon (coke), and H-2 over the carbon support. Th ...
Total syntheses of (±)-goniomitine, (±)-1,2-dehydroaspidospermidine, (±)-aspidospermidine, (±)-vincadifformine, and (±)-kopsihainanine A were achieved featuring two common key steps: (1) a palladium-catalyzed decarboxylative vinylation that provides quick ...
An analysis about the effect of carbon enrichment of allylhydridopolycarbosilane SMP10® with divinylbenzene (DVB) as a promising material for electrical conductive micro-electrical mechanical systems (MEMS) is presented. The liquid precursors can be microp ...
This thesis describes a unified strategy for the synthesis of monoterpene indole alkaloids of the Aspidosperma family. These syntheses feature two key steps: (1) a palladiumcatalyzed decarboxylative vinylation that provides quick access to cyclopentene int ...
One of the greatest sources of uncertainty in the science of anthropogenic climate change is from aerosol-cloud interactions. The activation of aerosols into cloud droplets is a direct microphysical linkage between aerosols and clouds; parameterizations of ...
Structured hierarchical catalysts were developed for efficient reduction of bromates in water. In the catalysts a small amount of active metal, 0.3 wt.% Pd, is supported onto carbon nanofibres grown either on sintered metal fibres or on a carbon cloth. In ...
Thousands of organic micropollutants and their transformation products occur in water. Although often present at low concentrations, individual compounds contribute to mixture effects. Cell-based bioassays that target health-relevant biological endpoints m ...
Effect of several usually used carbon materials on Pd catalyst for formic acid electrooxidation reaction is studied by physical characterization and electrochemical measurements. New active sites are formed due to the Pd and carbon interaction which is con ...