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Concept
Nacre
Summary
Nacre (ˈneɪkər , ˈnækrə ), also known as mother of pearl, is an organicinorganic composite material produced by some molluscs as an inner shell layer. It is also the material of which pearls are composed. It is strong, resilient, and iridescent.
Nacre is found in some of the most ancient lineages of bivalves, gastropods, and cephalopods. However, the inner layer in the great majority of mollusc shells is porcellaneous, not nacreous, and this usually results in a non-iridescent shine, or more rarely in non-nacreous iridescence such as flame structure as is found in conch pearls.
The outer layer of cultured pearls and the inside layer of pearl oyster and freshwater pearl mussel shells are made of nacre. Other mollusc families that have a nacreous inner shell layer include marine gastropods such as the Haliotidae, the Trochidae and the Turbinidae.
Nacre is composed of hexagonal platelets of aragonite (a form of calcium carbonate) 10–20 μm wide and 0.5 μm thick arranged in a continuous parallel lamina. Depending on the species, the shape of the tablets differs; in Pinna, the tablets are rectangular, with symmetric sectors more or less soluble. Whatever the shape of the tablets, the smallest units they contain are irregular rounded granules. These layers are separated by sheets of organic matrix (interfaces) composed of elastic biopolymers (such as chitin, lustrin and silk-like proteins).
Nacre appears iridescent because the thickness of the aragonite platelets is close to the wavelength of visible light. These structures interfere constructively and destructively with different wavelengths of light at different viewing angles, creating structural colours.
The crystallographic c-axis points approximately perpendicular to the shell wall, but the direction of the other axes varies between groups. Adjacent tablets have been shown to have dramatically different c-axis orientation, generally randomly oriented within ~20° of vertical. In bivalves and cephalopods, the b-axis points in the direction of shell growth, whereas in the monoplacophora it is the a-axis that is this way inclined.
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