Concept

Hydrogen cyanide

Related publications (32)

Photochemistry of 1- and 2-Naphthols and their Water Clusters: The Role of 1ππ*(La) Mediated Hydrogen Transfer to Carbon Atoms

The computational analysis of isomer- and conformer- dependent photochemistry of 1- and 2-naphthols and their microsolvated water clusters is motivated by their very different excited state reactivity. We present evidence that 1- and 2-naphthol follow dist ...

Wiley-V C H Verlag Gmbh2017

Hydrogen reduction of molybdenum oxide at room temperature

Frank Nüesch, Roland Hany

The color changes in chemo-and photochromic MoO3 used in sensors and in organic photovoltaic (OPV) cells can be traced back to intercalated hydrogen atoms stemming either from gaseous hydrogen dissociated at catalytic surfaces or from photocatalytically sp ...

Springer Nature2017

Effect of Very High Charge Density and Monomer Constitution on the Synthesis and Properties of Cationic Polyelectrolytes

Jutta Christine Wandrey, Ricardo Losada Mateo, Hamideh Ahmadloo

The free-radical homopolymerization of 1,3-bis(N,N,N-trimethylammonium)-2-propylmethacrylate dichloride (di-M) and 1,3-bis(N,N,N-trimethylammonium)-2-propylacrylate dichloride (di-A) in aqueous solution yields cationic polyelectrolytes (PEL) with theoretic ...

Mdpi Ag2016

Hydrogen–vacancy–dislocation interactions in α-Fe

William Curtin, Ali Tehranchi, Xi Zhang

Atomistic simulations of the interactions between dislocations, hydrogen atoms, and vacancies are studied to assess the viability of a recently proposed mechanism for the formation of nanoscale voids in Fe-based steels in the presence of hydrogen. Quantum- ...

Institute of Physics2016

A Functional Model of [Fe]-Hydrogenase

Rosario Scopelliti, Xile Hu, Matthew Wodrich, Tao Xu, Simona Mazza

[Fe]-Hydrogenase catalyzes the hydrogenation of a biological substrate via the heterolytic splitting of molecular hydrogen. While many synthetic models of [Fe]-hydrogenase have been prepared, none yet are capable of activating H-2 on their own. Here, we re ...

American Chemical Society2016

Synthesis and Reactivity of Mononuclear Iron Models of [Fe]-Hydrogenase that Contain an Acylmethylpyridinol Ligand

Xile Hu, Dafa Chen, Bowen Hu

[Fe]-hydrogenase has a single iron-containing active site that features an acylmethylpyridinol ligand. This unique ligand environment had yet to be reproduced in synthetic models; however the synthesis and reactivity of a new class of small molecule mimics ...

Wiley-V C H Verlag Gmbh2014

Homogeneous Catalytic Dehydrogenation of Formic Acid: Progress Towards a Hydrogen-Based Economy

Paul Joseph Dyson, Gabor Laurenczy

One of the limiting factors to a hydrogen-based economy is associated with the problems storing hydrogen. Many different approaches are under evaluation and the optimum approach will not be the same for all applications, i.e., static, mobile, small and lar ...

2014

WMe6 Tamed by Silica: Si-O-WMe5 as an Efficient, Well-Defined Species for Alkane Metathesis, Leading to the Observation of a Supported W-Methyl/Methylidyne Species

David Lyndon Emsley, Aaron James Rossini

The synthesis and full characterization of a well-defined silica-supported :Si-O-W(Me)(5) species is reported. Under an inert atmosphere, it is a stable material at moderate temperature, whereas the homoleptic parent complex decomposes above -20 degrees C, ...

AMER CHEMICAL SOC2014

Uvudf: Ultraviolet Imaging Of The Hubble Ultra Deep Field With Wide-Field Camera 3

Hakim Atek

We present an overview of a 90 orbit Hubble Space Telescope treasury program to obtain near-ultraviolet imaging of the Hubble Ultra Deep Field using the Wide Field Camera 3 UVIS detector with the F225W, F275W, and F336W filters. This survey is designed to: ...

Institute of Physics2013

A bright tetranuclear iridium(III) complex

Michael Graetzel, Mohammad Khaja Nazeeruddin, Rosario Scopelliti, Davide Di Censo

A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most inte ...

2011

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