Publications related to Adduct

Recent Advances in Group 14 and 15 Lewis Acids for Frustrated Lewis Pair Chemistry

Frustrated Lewis pairs (FLP) which rely on the cooperative action of Lewis acids and Lewis bases, played a prominent role in the advancement of main-group catalysis. While the early days of FLP chemistry witnessed the dominance of boranes, there is a growi ...

WILEY-V C H VERLAG GMBH2022

Benzodithiophene‐Based Spacers for Layered and Quasi‐Layered Lead Halide Perovskite Solar Cells

Kevin Sivula, Jun Ho Yum, Mounir Driss Mensi, Liang Yao, Nestor Guijarro Carratala, Han-Hee Cho, Barbara Alexandra Primera Darwich, Luc Emile Monnier

Incorporating extended pi-conjugated organic cations in layered lead halide perovskites is a recent trend promising to merge the fields of organic semiconductors and lead halide perovskites. Herein, we integrate benzodithiophene (BDT) into Ruddlesden–Poppe ...

2021

A Two Step Postsynthetic Modification Strategy: Appending Short Chain Polyamines to Zn-NH2-BDC MOF for Enhanced CO2 Adsorption

Wendy Lee Queen, Jordi Espin Marti, Mehrdad Asgari, Olga Trukhina, Ilia Kochetygov, Anita Justin

Functionalizing metal–organic frameworks (MOFs) with amines is a commonly used strategy to enhance their performance in CO2 capture applications. As such, in this work, a two-step strategy to covalently functionalize NH2-containing MOFs with short chain po ...

2021

Bronsted and Lewis acid adducts of triazenes

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Abdusalom Suleymanov, Iris Roswitha Landman, Frederick Mark Chadwick

The synthetic utility of triazenes rests on the fact that the triazene function can be cleaved by BrOnsted or Lewis acids, liberating diazonium compounds. However, the preferred coordination site of the acid is still a matter of debate. We have analyzed tr ...

2020

In Situ Formation of Frustrated Lewis Pairs in a Water-Tolerant Metal-Organic Framework for the Transformation of CO2

Paul Joseph Dyson, Fatmah Ebrahim, Serhii Shyshkanov, Kyriakos Stylianou, Ngoc Tú Nguyên

Frustrated Lewis pairs (FLPs) consist of sterically hindered Lewis acids and Lewis bases, which provide high catalytic activity towards non-metal-mediated activation of "inert" small molecules, including CO2 among others. One critical issue of homogeneous ...

2019

Towards a frustrated Lewis pair-ionic liquid system

Paul Joseph Dyson, Rosario Scopelliti, Gabor Laurenczy, Zhaofu Fei, Felix Daniel Bobbink, Emilia Paunescu, Florian Gérald Abela

An ionic liquid encompassing a bulky tertiary amine was synthesized and used as a dual solvent-reactant for the formation of a frustrated Lewis pair with tris(pentafluorophenyl) borane, forming a pseudo-frustrated Lewis pair-ionic liquid system. The ionic ...

Elsevier2018

Fixation of nitrous oxide by mesoionic and carbanionic N-heterocyclic carbenes

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Euro Solari, Giacomo Cecot, Léonard Yannick Maurice Eymann

A ditopic carbanionic N-heterocyclic carbene was found to react with the inert gas nitrous oxide, resulting in a stable covalent adduct with two intact N2O groups attached to the heterocycle. Mesoionic N-heterocyclic carbenes derived from C2-arylated 1,3-b ...

Royal Soc Chemistry2017

Surface Reaction Barriometry: Methane Dissociation on Flat and Stepped Transition-Metal Surfaces

Rainer Beck, Ana Gutiérrez González, Helen Jane Chadwick, Francesco Nattino

Accurately simulating heterogeneously catalyzed reactions requires reliable barriers for molecules reacting at defects on metal surfaces, such as steps. However, first- principles methods capable of computing these barriers to chemical accuracy have yet to ...

Amer Chemical Soc2017

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Adduct

Recent Advances in Group 14 and 15 Lewis Acids for Frustrated Lewis Pair Chemistry

Benzodithiophene‐Based Spacers for Layered and Quasi‐Layered Lead Halide Perovskite Solar Cells

Investigating Tetrel-Based Neutral Frustrated Lewis Pairs for Hydrogen Activation

A Two Step Postsynthetic Modification Strategy: Appending Short Chain Polyamines to Zn-NH2-BDC MOF for Enhanced CO2 Adsorption

Bronsted and Lewis acid adducts of triazenes

In Situ Formation of Frustrated Lewis Pairs in a Water-Tolerant Metal-Organic Framework for the Transformation of CO2

Towards a frustrated Lewis pair-ionic liquid system

Dyes, Radicals and Nitrous Oxide Adducts Derived from N-Heterocyclic Carbenes

Fixation of nitrous oxide by mesoionic and carbanionic N-heterocyclic carbenes

Surface Reaction Barriometry: Methane Dissociation on Flat and Stepped Transition-Metal Surfaces

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Recent Advances in Group 14 and 15 Lewis Acids for Frustrated Lewis Pair Chemistry

Bronsted and Lewis acid adducts of triazenes

A Two Step Postsynthetic Modification Strategy: Appending Short Chain Polyamines to Zn-NH2-BDC MOF for Enhanced CO2 Adsorption

Towards a frustrated Lewis pair-ionic liquid system

Benzodithiophene‐Based Spacers for Layered and Quasi‐Layered Lead Halide Perovskite Solar Cells

Surface Reaction Barriometry: Methane Dissociation on Flat and Stepped Transition-Metal Surfaces

Investigating Tetrel-Based Neutral Frustrated Lewis Pairs for Hydrogen Activation

In Situ Formation of Frustrated Lewis Pairs in a Water-Tolerant Metal-Organic Framework for the Transformation of CO2

Dyes, Radicals and Nitrous Oxide Adducts Derived from N-Heterocyclic Carbenes

Fixation of nitrous oxide by mesoionic and carbanionic N-heterocyclic carbenes