Stratosphere

The stratosphere (ˈstrætəˌsfɪər,_-toʊ-) is the second layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. The stratosphere is an atmospheric layer composed of stratified temperature layers, with the warm layers of air high in the sky and the cool layers of air in the low sky, close to the planetary surface of the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer. The temperature inversion is in contrast to the troposphere, near the Earth's surface, where temperature decreases with altitude. Between the troposphere and stratosphere is the tropopause border that demarcates the beginning of the temperature inversion. Near the equator, the lower edge of the stratosphere is as high as , at midlatitudes around , and at the poles about . Temperatures range from an average of near the tropopause to an average of near the mesosphere. Stratospheric temperatures also vary within the stratosphere as the seasons change, reaching particularly low temperatures in the polar night (winter). Winds in the stratosphere can far exceed those in the troposphere, reaching near in the Southern polar vortex. The mechanism describing the formation of the ozone layer was described by British mathematician Sydney Chapman in 1930, and is known as the Chapman cycle or ozone–oxygen cycle. Molecular oxygen absorbs high energy sunlight in the UV-C region, at wavelengths shorter than about 240 nm. Radicals produced from the homolytically split oxygen molecules combine with molecular oxygen to form ozone. Ozone in turn is photolysed much more rapidly than molecular oxygen as it has a stronger absorption that occurs at longer wavelengths, where the solar emission is more intense. Ozone (O3) photolysis produces O and O2. The oxygen atom product combines with atmospheric molecular oxygen to reform O3, releasing heat. The rapid photolysis and reformation of ozone heat the stratosphere, resulting in a temperature inversion.