Concept
Endergonic reaction
Related publications (37)
A Cobalt Nanocatalyst for the Hydrogenation and Oxidative Dehydrogenation of N-heterocycles
Paul Joseph Dyson, Mingyang Liu, Xiang Li, Yelin Hu, Matthias Beller
Catalytic hydrogenation and oxidative dehydrogenation of N-heterocycles to produce tetrahydroquinoline and quinoline derivatives are important reactions of particular importance in the agrochemical and pharmaceutical industries. Herein, we report earth-abu ...
Weinheim2023Atomic Level Insights of Non-Noble Metal Catalysts for the Oxygen Evolution Reaction
The conversion of intermittent renewable energy resources in the form of chemical bond, such as hydrogen production from electrochemical water splitting, is a promising way to satisfy the future global energy demand and address the environmental issues. Th ...
EPFL2021Atomistic dynamics of elimination and nucleophilic substitution disentangled for the F- + CH3CH2Cl reaction
Chemical reaction dynamics are studied to monitor and understand the concerted motion of several atoms while they rearrange from reactants to products. When the number of atoms involved increases, the number of pathways, transition states and product chann ...
NATURE PORTFOLIO2021Natural Product Synthesis Enabled by Domino Processes Incorporating a 1,2-Rearrangement Step
Qian Wang, Jieping Zhu, Bastien Delayre
The art of natural product total synthesis is closely associated with two major determinants: the development/application of novel chemical reactions and the innovation in strategic use of classic organic reactions. While purposely seeking/applying a new s ...
2021Structure and reactivity of the polarised liquid–liquid interface: what we know and what we do not
Hubert Girault, Astrid Johana Olaya Avendano, Pekka Eero Peljo, Grégoire Clément Gschwend
Charge transfer phenomena at the interface between two immiscible electrolyte solutions (ITIES) are electrochemical reactions taking place in soft media. Owing to their liquid nature, the ITIES shows a large panel of electrochemical reactions including ele ...
2020Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps
A major goal in the design of synthetic molecular machines is the creation of pumps that can use the input of energy to transport material from a reservoir at low chemical potential to a different reservoir at higher chemical potential, thereby forming and ...
ROYAL SOC CHEMISTRY2020Exploring Perovskite-Metal Nanoassemblies for Photocatalytic Applications
The development of sustainable, renewable and economic chemical processes lies in the centre of todayâs global energy challenge. Like in plants, artificial photosynthesis offers an auspicious solution in harvesting solar energy and storing it in chemical ...
EPFL2020Mechanistic study of the photo‐generation of hydrogen by decamethylruthenocene
Hubert Girault, Pekka Eero Peljo, Manuel Alejandro Méndez Agudelo, Heron Vrubel, Micheal Diarmaid Scanlon, Laurent Alexis Clément Vannay, Sunny Isaïe Maye, Lucie Josette Renée Rivier
Hydrogen evolution by decamethylruthenocene (Cp*2RuII) was studied in detail highlighting that metallocenes are capable of photo‐reducing hydrogen without the need of an additional sensitizer. Electrochemical, gas chromatographic and spectroscopic (UV/vis, ...
2019Stability of metallo-porphyrin networks under oxygen reduction and evolution conditions in alkaline media
Klaus Kern, Jan Gui-Hyon Dreiser, Markus Etzkorn, Claudius Morchutt, Sebastian Stepanow, Benjamin Wurster
Transition metal atoms stabilised by organic ligands or as oxides exhibit promising catalytic activity for the electrocatalytic reduction and evolution of oxygen. Built-up from earth-abundant elements, they offer affordable alternatives to precious-metal b ...
2019Gas-Phase Ozone Reactions with a Structurally Diverse Set of Molecules: Barrier Heights and Reaction Energies Evaluated by Coupled Cluster and Density Functional Theory Calculations
Jeremy Samuel Arey, Peter Rudolf Tentscher, Daniela Trogolo
Reactions with ozone transform organic and inorganic molecules in water treatment systems as well as in atmospheric chemistry, either in the aqueous phase, at gas/particle interfaces, or in the gas phase. Computed thermokinetic data can be used to estimate ...
AMER CHEMICAL SOC2019