Concept

Carbonic acid

Related publications (90)

Reaction of Ferrate(VI) with ABTS and Self-Decay of Ferrate(VI): Kinetics and Mechanisms

Reactions of ferrate(VI) during water treatment generate perferryl(V) or ferryl(IV) as primary intermediates. To better understand the fate of perferryl(V) or ferryl(IV) during ferrate(VI) oxidation, this study investigates the kinetics, products, and mech ...

Amer Chemical Soc2014

The Use of Passive Samplers to Reveal Industrial and Agricultural Pollution Trends in Swiss Rivers

Luiz Felippe De Alencastro, Nicolas Estoppey, Julien Omlin, Adrien Schopfer, Robin Udrisard

This study shows the efficiency of passive sampling to reveal industrial and agricultural pollution trends. Two practical applications for nonpolar and polar contaminants are presented. Low-density polyethylene (LDPE) samplers were deployed for one year in ...

Schweizerische Chemische Gesellschaft2014

Homogeneous Catalytic Dehydrogenation of Formic Acid: Progress Towards a Hydrogen-Based Economy

Paul Joseph Dyson, Gabor Laurenczy

One of the limiting factors to a hydrogen-based economy is associated with the problems storing hydrogen. Many different approaches are under evaluation and the optimum approach will not be the same for all applications, i.e., static, mobile, small and lar ...

2014

Direct Carbon Dioxide Hydrogenation into Formic Acid in Acidic Media

Séverine Joëlle Moret

A major challenge in the face of increasing global energy demand is the development of alternative environmentally friendly and renewable energy resources. Hydrogen is an excellent energy carrier, but has drawbacks in storage density and is dangerous to ha ...

EPFL2014

Low-cost industrially available molybdenum boride and carbide as “platinum-like” catalysts for the hydrogen evolution reaction in biphasic liquid systems

Hubert Girault, Xile Hu, Kurt Schenk, Heron Vrubel, Micheal Diarmaid Scanlon, Véronique Amstutz

Rarely reported low-cost molybdenum boride and carbide microparticles, both of which are available in abundant quantities due to their widespread use in industry, adsorb at aqueous acid–1,2-dichloroethane interfaces and efficiently catalyse the hydrogen ev ...

Royal Soc Chemistry2013

Classical and non-classical phosphine-Ru(ii)-hydrides in aqueous solutions: many, various, and useful

Gabor Laurenczy

Hydrogenation of the water-soluble [{RuCl2(mtppms)(2)}(2)] (mtppms = monosulfonated triphenylphosphine) was studied in aqueous solutions in the presence of excess mtppms both with H-2 and with aqueous HCOONa. Depending on the reductant, the pH and H-2 pres ...

Royal Soc Chemistry2013

Amino-functionalized macroporous silica for efficient tryptic digestion in acidic solutions

Hubert Girault, Liang Qiao, Jingjing Wan

Amino-functionalized macroporous silica foam (NH2-MOSF) has been developed as a host reactor to realize highly efficient proteolysis in acidic solutions where normal tryptic reactions cannot occur. The digestion protocol consists simply of adding the funct ...

Wiley-Blackwell2013

Lactate brain metabolism in different mouse strains probed by hyperpolarized 13C MRS

Rolf Gruetter, Bernard Lanz, Mor-Miri Mishkovsky, Tian Cheng, Arnaud Comment, Josefina Adriana Maria Bastiaansen, Yuhei Takado

Lactate plays an important role in brain energetics and is essential for neuronal function. Alteration of its metabolism might be associated with mechanisms linked to neurodegenerative disorders1. The purpose of this study was to demonstrate the potential ...

2013

Acid-base properties of the N3 ruthenium(II) solar cell sensitizer: a combined experimental and computational analysis

Mohammad Khaja Nazeeruddin, Filippo de Angelis

We report a combined spectro-photometric and computational investigation of the acid-base equilibria of the N3 solar cell sensitizer [Ru(dcbpyH(2))(2)(NCS)(2)] (dcbpyH(2) = 4,4'-dicarboxyl-2,2' bipyridine) in aqueous/ethanol solutions. The absorption spect ...

Royal Society of Chemistry2012

Bridging Static and Dynamical Descriptions of Chemical Reactions: An ab Initio Study of CO2 Interacting with Water Molecules

Wanda Andreoni, Fabio Pietrucci

Extracting reliable thermochemical parameters from molecular dynamics simulations of chemical reactions, although based on ab initio methods, is generally hampered by difficulties in reproducing the results and controlling the statistical errors. This is a ...

Amer Chemical Soc2012

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