Are you an EPFL student looking for a semester project?
Work with us on data science and visualisation projects, and deploy your project as an app on top of Graph Search.
Concept
Fast ion conductor
Summary
In materials science, fast ion conductors are solid conductors with highly mobile ions. These materials are important in the area of solid state ionics, and are also known as solid electrolytes and superionic conductors. These materials are useful in batteries and various sensors. Fast ion conductors are used primarily in solid oxide fuel cells. As solid electrolytes they allow the movement of ions without the need for a liquid or soft membrane separating the electrodes. The phenomenon relies on the hopping of ions through an otherwise rigid crystal structure.
Fast ion conductors are intermediate in nature between crystalline solids which possess a regular structure with immobile ions, and liquid electrolytes which have no regular structure and fully mobile ions. Solid electrolytes find use in all solid-state supercapacitors, batteries, and fuel cells, and in various kinds of chemical sensors.
In solid electrolytes (glasses or crystals), the ionic conductivity Ωi can be any value, but it should be much larger than the electronic one. Usually, solids where Ωi is on the order of 0.0001 to 0.1 Ohm−1 cm−1 (300 K) are called superionic conductors.
Proton conductors are a special class of solid electrolytes, where hydrogen ions act as charge carriers. One notable example is superionic water.
Superionic conductors where Ωi is more than 0.1 Ohm−1 cm−1 (300 K) and the activation energy for ion transport Ei is small (about 0.1 eV), are called advanced superionic conductors. The most famous example of advanced superionic conductor-solid electrolyte is RbAg4I5 where Ωi > 0.25 Ohm−1 cm−1 and Ωe ~10−9 Ohm−1 cm−1 at 300 K. The Hall (drift) ionic mobility in RbAg4I5 is about 2 cm2/(V•s) at room temperatures. The Ωe – Ωi systematic diagram distinguishing the different types of solid-state ionic conductors is given in the figure.
No clear examples have been described as yet, of fast ion conductors in the hypothetical advanced superionic conductors class (areas 7 and 8 in the classification plot). However, in crystal structure of several superionic conductors, e.
Official source
About this result
This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.