Supercapacitor | EPFL Graph Search

A supercapacitor (SC), also called an ultracapacitor, is a high-capacity capacitor, with a capacitance value much higher than other capacitors but with lower voltage limits. It bridges the gap between electrolytic capacitors and rechargeable batteries. It typically stores 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much faster than batteries, and tolerates many more charge and discharge cycles than rechargeable batteries. Supercapacitors are used in applications requiring many rapid charge/discharge cycles, rather than long-term compact energy storage — in automobiles, buses, trains, cranes and elevators, where they are used for regenerative braking, short-term energy storage, or burst-mode power delivery. Smaller units are used as power backup for static random-access memory (SRAM). Unlike ordinary capacitors, supercapacitors do not use the conventional solid dielectric, but rather, they use electrostatic do

Ageing of porous carbon electrodes

Manxi Zhu

Ultracapacitors, also called electrochemical double layer capacitors (EDLC) or supercapacitors, may improve the performance of conventional electrolytic capacitors in terms of specific energy, or improve the performance of rechargeable batteries in terms of specific power when combined with respective device. However, the application of ultracapacitors faces the problem of ageing – the deterioration of capacity and increase of equivalent series resistance of the system. This thesis intends to elucidate ageing mechanisms of ultracapacitors based on activated carbon electrodes with tetrafluoroborate in acetonitrile as electrolyte. Multi-method experimental investigations are presented which allow to obtain a comprehensive picture of ageing. Ultracapacitors were electrochemically aged under various conditions by applying voltages and temperatures close to the actual operation conditions. The influences of ageing on the electrodes were investigated by structural and chemical characterization. Gas volumetric measurement (porosimetry) and Raman spectroscopy were applied to follow the structural changes; elemental analysis, electron spectroscopy for chemical analysis (ESCA, XPS) and attenuated total reflection infrared spectroscopy (ATR-IR) were applied for chemical composition analysis. It was found that the changes of both structure and chemical composition, which occur on aged anodes and cathodes, are asymmetric. Aged anodes showed more significant changes such as stronger decrease of pore volume and specific area, and more complex chemical species. Chemically bound nitrogen species were found only on aged anodes, but not on fresh electrodes and aged cathodes. Based on the experimental results, several mechanisms for ageing are suggested. The functionalities in activated carbons play an important role for ageing. Various oxygen-containing functional groups can take part in the reactions. A higher amount of functionalities means that more electroactive sites can be found on the graphene sheets in activated carbons to promote electrochemical reactions. Thus one can assume that less functional groups in activate carbons would be preferable for the stability of ultracapacitors. Ageing tests were carried out on individual components of the electrodes, mainly on activated carbon powders and conductive carbon additives. Observations are consistent with those on assembled electrodes. It turned out that the activated carbons from synthetic resin precursors, which have fewer oxygen functional groups, suffer less from ageing than those from natural precursors with more oxygen functional groups. A similar phenomenon was also observed on the conductive agents.

EPFL2006

Supercapacitor Thermal Modeling and Characterization in Transient State for Industrial Applications

Roland Gallay

A new thermal model, which allows temperature distribution determination inside a supercapacitor cell, is developed. The model is tested for a supercapacitor based on the activated carbon and organic electrolyte technology. In hybrid vehicle applications, supercapacitors are used as energy-storage devices, offering the possibility of providing the peak-power requirement. They are charged and discharged at a high current rate The problem with this operating mode is the large amount of heat produced in the device which can lead to its destruction. An accurate thermal modeling of the internal temperature is required to design a cooling system for supercapacitor module, meeting the safety and reliability of the power systems. The purpose of this paper is to study the supercapacitor temperature distribution in steady and transient states. A thermal model is developed; it is based on the finite-differential method which allows for the supercapacitor thermal resistance determination. The originality of this paper is in the fact that a thermocouple (type K) was placed inside the supercapacitor from Maxwell Technologies. A test bench is realized. The cases of supercapacitor thermal distribution using natural and forced convection are studied. Simulations and experimental results are reported to validate the proposed model. The results obtained with this model may be used to determine the cooling system required for actual supercapacitor applications.

2009

A Fully Integrated Counter Flow Energy Reservoir for Peak Power Delivery in Small Form-Factor Sensor Systems

Yao Shi

We present a fully integrated energy reservoir unit using a counter flow method for peak power delivery in space-constrained sensor systems. Recent advances in circuits have enabled significant reduction in the size of wireless systems such as implantable biomedical devices. As a consequence, the batteries integrated in these systems have also shrunk, resulting in high internal resistances (~10 kQ). However, the peak current requirement of power-hungry components such as radios remains in the milliwatt range and hence cannot directly be supplied from the battery. Therefore, an energy reservoir with high output power but small size is required. We present an efficient energy reservoir that dynamically reconfigures a storage capacitor array using a so-called counter flow approach. By creating a voltage gradient on capacitor arrays and moving the capacitors along the slope of the gradient, the supply voltage can be maintained while the energy stored in the reservoir is delivered efficiently to the load. The counter flow energy reservoir delivers 65% of stored energy before recharging is needed which allows up to a 12× reduction in overall capacitor size compared with our implementation of the previous method. The design supplies up to 13.6-mW output power for 1 μs. We demonstrate the proposed concept with a pulsed radio, showing an 11.5× increase in pulse length compared with the previous method.

IEEE2017

Ageing of porous carbon electrodes

Manxi Zhu

EPFL2006