Chromium | EPFL Graph Search

Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardness. A major development in steel production was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel. Stainless steel and chrome plating (electroplating with chromium) together comprise 85% of the commercial use. Chromium is also greatly valued as a metal that is able to be highly polished while resisting tarnishing. Polished chromium reflects almost 70% of the visible spectrum, and almost 90% of infrared light. The name of the element is derived from the Greek word χρῶμα, chrōma, meaning color, because many chromium compounds are intensely colored. Industrial production of chromium proceeds from chromite ore (mostly FeCr2O4) to produce ferrochromium, an iron-

Preliminary analysis of the PETALE program and comparison to simulations

Thomas Jean-François Ligonnet

This Master thesis focus on a preliminary analysis of the experimental data obtained during the PETALE program in the CROCUS reactor at EPFL. The objective of PETALE is to validate neutron nuclear data for stainless steel and its main elements –namely iron, nickel, and chromium– and to contribute to the reduction of their uncertainties. For this purpose, transmission experiments were performed using activation dosimetry in separate reflectors made of the four materials. The manuscript is separated in three main parts. In the first part, after a presentation of the experimental setup, the measured spectra of the irradiated dosimeters are analysed. The results obtained with the methodology developed at EPFL are compared with those obtained by the collaboration partner CEA. The second part details two supplementary studies. First an experiment was performed and analysed to assess the impact of position uncertainties of core centre dosimeters. It was estimated to be 0.14 % for a position uncertainty of ±5 mm. The second study dealt with the estimation of PETALE’s monitors dead time. A dead time correction model was applied on a stable period experiment, and validated against activation dosimetry experiments. The power underestimation was estimated at 5 % at 80 W. The last part presents a comparison between experimental results and Serpent simulations of PETALE’s experiments using the JEFF-3.3 nuclear data library. In total twenty experiments were modelled and compared with their respective experiment. In this preliminary study, the results show a general agreement in the thermal range. An underestimation of the transparency of nickel and chromium for neutron with an energy of 2 MeV is observed. At higher energies, around 8 MeV, the chromium transparency is strongly overestimated. Finally, only a slight overestimation of the transparency to 2 MeV neutron is observed for iron and stainless steel reflectors. Outlooks are provided for the next steps of the analysis and validation, as well as for prospects on a longer term.

2021

Typologie des eaux souterraines de la molasse entre Chambéry et Linz (France, Suisse, Allemagne, Autriche)

The geochemical typology of natural subsurface waters of the Molasse basin is part of the AQUITYP project, initiated by the Geology Laboratory (GEOLEP) of the Swiss Federal Institute of Technology in Lausanne (EPFL). This study provides an overview of the variation in space of the hydrochemical parameters, especially of trace elements, in order to determine the geological origin of their aquifers. Our data base is mainly made up of two observation networks: a subsurface water network and a deep groundwater network. Complete analyses of all samples have been executed using standard methods for anions and silicium, and high resolution inductively coupled mass spectrometry (HR-ICP-MS) for major cations and trace elements down to the detection limit of about 0.2 µg/l. Subsurface water network It is the main observation network of this investigation and comprises 112 water samples from different springs, collected all over the Molasse basin between Chambéry (France) and Linz (Austria), but mainly in the Swiss Molasse basin. For this region, four groups are generally distinguished, according to the sediment deposition in a continental or marine environment, in ascending stratigraphic order: (1) the Lower Marine Molasse (UMM and North Helvetic "flysch" p.p.), (2) the Lower Freshwater Molasse (USM), (3) the Upper Marine Molasse (OMM) and (4) the Upper Freshwater Molasse (OSM). Our water samples originate from typical sedimentary deposits which we divided in about 30 different sub-type aquifers according to their geological origin and their depositional environment. They are defined on the basis of lithological and structural homogeneity. Therefore, only catchments that completely drain a single, lithologically homogenous, Molasse terrain unit are considered here. Spring catchments selected were generally not affected by runoff from towns, or paved roads. Agricultural activities have been avoided as well as possible. Such spring water should be free of major human influences and only in few cases contain a certain amount of fertilizer products (p.ex: nitrates). Leachate tests of crushed rocks and comparison with snow and soil water compositions allowed to decipher the geogene origin of the dissolved ions in natural groundwaters. The water withdrawn can be generally classified as a calcium-magnesium-hydrogenocarbonate (Ca-Mg-HCO3)-type water. The trace analyses allowed to distinguish several subtypes within this homogenous water type group. The general spacial distribution of the trace elements show, that spring waters in the Bavarian Molasse basin are caracterized by elements as lithium and uranium linked to acid rocks, while those of the Swiss Molasse basin are preferentially influenced by elements derived from mafic or ultramafic rocks, such as chromium and cobalt. The following elements show specific links between aquifer rock type and groundwater. Sulfates: Total mineralisation of spring waters issued from the gypse-bearing Molasse (USM) and the "Glimmersande" (OSM) are highly influenced by high sulfate contents. It can be demonstrated that sulfate ions are produced from two different sources within this two sub-type aquifers: from the dissolution of gypsum in water, producing high calcium contents as well, and from the oxydation of sulfurous ore minerals, especially pyrite, which are abundant in the "Glimmersande". The "Glimmersand" aquifers in NE Switzerland are furtheron caracterized by high lithium, molybdenum and uranium concentrations, reflecting the granitic composition of this sandstones. High barium contents (>150 µg/l) have been found in spring waters issued from aquifers with a dominant fissure permeability ("Grès de la Cornalle", "Gibloux-Delta" and "Rigi-Schüttung"). Its origin is supposed to be the mineral barite, which tends to precipitate in fractures. Therefore, high barium concentrations may indicate the presence of fracture flow within the aquifer. Considerably high silicon contents are linked to the quartzitic and fine grained aquifers of the brackish marine molasse in Bavaria. Both, petrographical composition and slow flow rate are favouring the water-rock interaction. Caracteristic lithium footprints are found in several waters, as in the aquifers composed of the "Glimmersande", the gypse-bearing molasse, the Rigi-conglomerates, the brackish and the estuarine marine molasse. Chromium strongly marks the waters originating from the Swiss marine Molasse aquifers. It is probably related to ophiolithic detritus derived from the flysch of the Prealpes. A couple of waters show weak anomalies of cobalt, which are nevertheless intimately linked to the presence of ophiolithic components in the sediments. Cobalt might be used as a hydrostratigraphical tool to identify greenstone inputs. Analysed colloidal aluminum may serve as a hydrodynamical parameter, indicating microturbidity within the aquifer. High amounts of aluminum varying in time, have been found in estuarin deposits of the OMM. Generally speaking, we propose three main origins of trace elements in the spring water of the Molasse basin: presence of certain petrographical components within the sediments such as basic and ultrabasic rocks, heavy minerals and evaporites. a small flow rate through interstitial porosity of fine grained sediments, favouring water-rock interaction. the abundance of colloidal material in the waters which depends on the petrographical composition of the aquifer and on sample treatment, e.g. filtration techniques. Deep groundwater network A second observation network composed of 21 borehole waters has been added for comparison. Compared to the subsurface waters, deep water chemistry might differ. The following reasons seem to be responsible: Long residence times of water in the underground favours slow reaction kinetics. Chemistry of very deep water can be influenced by mixing with older formation waters. Most of the deep boreholes in the Swiss Molasse basin are situated in the OMM and therefore represent a likely homogenous lithology. Borehole waters, because of different aquifer rock types and unknown surface and borehole influences, are least likely to represent typical Molasse water composition.

EPFL1995

Assainissement de la décharge de Colliare à Penthaz – Etude de variantes

Gabrielle Hack

The landfill of Colliare is situated on the left bank of the river « la Venoge », at the place of a former gravel pit in the municipality of Penthaz. It was exploited until 1995 and many different wastes were deposited in it, such as incineration slag of household waste, grinding of cars, residues of biostabilizer, waste of construction site and materials of excavation. A water pollution due to the presence of this landfill was noticed at the beginning of the nineties, mainly by ammonium and nitrite. In one measure chromium was also found in rather important concentration. The presence of these compounds in water reflects the existence of biodegradation of the organic matter present in the mass of waste. The concentration of ammonium being higher than the limit imposed by Swiss law, a remediation is necessary. Various projects of remediation were made during the last twenty years, the main being to clean up this former landfill in order to have the possibility of creating a new one for bioactive wastes. This project was rejected by the « Grand Conseil » and the remediation of the landfill was set aside during several years. Today, the question is to study various variants of remediation to define which one would be the best for Colliare. The choice of the variants was limited either to a containment of the landfill’s surface or to bioventing. This work studies the possible implantation of these two variants, by analysing their advantages and disadvantages so as to facilitate the choice of the final solution. For that purpose, laboratory analyses were made to define the list of contaminants present in the mass of waste that risk to contaminate the water near the landfill. It was demonstrated that beside the already turn out organic pollution, the landfill contains a huge quantity of PCB and PAH as well as several heavy metals such as chromium, lead or copper. Furthermore analyses to obtain information on the quantity of biodegradable organic matter were made. It was shown that organic matter constitues only a small percentage of the mass of waste. Landfill containment is not considered as a real remediation because the contaminants stay in the site. The solution is studied here because of the various types of contaminants present in the waste. Furthermore the time it takes to implement is relatively short and it is possible to put vegetation on the site just after the installation of the mineral cover. There are thus few impacts on the fauna and the flora and the contaminants are normally not a risk anymore for the water during all the life of the containment. Bioventing has as main advantage to be a real method of remediation. The problem of its implementation in the case of Colliare is the presence of PCB and PAH in the mass of waste. Indeed biodegradation would have no effect on these compounds and the risk of water contamination would not decrease thanks to bioventing. Furthermore the small percentage of organic matter does not justify the implementation of such an installation. Finally the costs of both variants were compared. Containment costs less than bioventing. Thus the cost of bioventing is too high to implement it in addition to containment except if the decrease of greenhouse gases emissions is enough important for being exchanged on the market of carbon. The solution chosen here is landfill containment, although it is not ideal for a real remediation of the site.

2011