Aerosol | EPFL Graph Search

An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be natural or anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, dust, steam from a kettle, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an anthropogenic aerosol. The liquid or solid particles in an aerosol have diameters typically less than 1 μm (larger particles with a significant settling speed make the mixture a suspension, but the distinction is not clear-cut). In general conversation, aerosol often refers to a dispensing system that delivers a consumer product from a can. Diseases can spread by means of small droplets in the breath, sometimes

CFD simulation of an aerosol mixing chamber

Andrea Giordano

In the last years, the correlation between air pollution and health issues related to respiratory, cardiovascular and digestive systems has become evident. Today, urban aerosols raise the interest of both scientific community and public opinion. METAS, the Swiss Federal Institute of Metrology, takes part in AeroTox, a European Union’s research project involving the development of a reference aerosol calibration infrastructure - a so-called mixing chamber. In this chamber, pure air and particles are injected on top and the resulting aerosol is sampled at the bottom. The quality of this aerosol is assessed according to its concentration homogeneity: the purpose of this master’s project is to improve it. In addition, two research questions were addressed. How much can the mixing chamber dimensions be reduced without affecting the concentration homogeneity? Dimensions are crucial because the mixing chamber must be transportable. Also, how much can the flow rates be reduced without affecting the concentration homogeneity? Computational Fluid Dynamics (CFD) simulations and experiments were employed. Numerical simulations were performed in COMSOL Multiphysics, implementing a particle tracing and a diluted species model. This allowed to investigate the structure of the flow and the involved mixing mechanisms: diffusion, convection and turbulent dispersion. However, only the diluted species model was successful. The simulated concentration at the outlet is perfectly homogeneous. Experiments were carried out using two particle size distributions: NaCl (size peak at 80 nm) and Polystyrene Latex (PSL, size peak at 900 nm). Empirical data validate simulations and show a concentration homogeneity within 5%. Furthermore, uncertainty on the measurements is of 4.24%: the simulated concentration homogeneity thus lies within the uncertainty of the experimental findings. Moreover, experiments show that salt particles reach a higher concentration homogeneity than PSL particles. Finally, in case of salt particles, experiments prove that the flow rates can be halved and even equalized and the length of the mixing chamber can be reduced to 50% without drastically affecting the concentration homogeneity.

2020

Light absorption by brown carbon over the South-East Atlantic Ocean

Athanasios Nenes, Lu Zhang

Biomass burning emissions often contain brown carbon (BrC), which represents a large family of light-absorbing organics that are chemically complex, thus making it difficult to estimate their absorption of incoming solar radiation, resulting in large uncertainties in the estimation of the global direct radiative effect of aerosols. Here we investigate the contribution of BrC to the total light absorption of biomass burning aerosols over the South-East Atlantic Ocean with different optical models, utilizing a suite of airborne measurements from the ORACLES 2018 campaign. An effective refractive index of black carbon (BC), m(eBC) = 1.95 + ik(eBC), that characterizes the absorptivity of all absorbing components at 660 nm wavelength was introduced to facilitate the attribution of absorption at shorter wavelengths, i.e. 470 nm. Most values of the imaginary part of the effective refractive index, k(eBC), were larger than those commonly used for BC from biomass burning emissions, suggesting contributions from absorbers besides BC at 660 nm. The TEM-EDX single-particle analysis further suggests that these long-wavelength absorbers might include iron oxides, as iron is found to be present only when large values of k(eBC) are derived. Using this effective BC refractive index, we find that the contribution of BrC to the total absorption at 470 nm (R-BrC,(470)) ranges from similar to 8 %-22 %, with the organic aerosol mass absorption coefficient (MAC(OA,470)) at this wavelength ranging from 0.30 +/- 0.27 to 0.68 +/- 0.08 m(2) g(-1). The core-shell model yielded much higher estimates of MAC(OA,470) and R(BrC,470)( )than homogeneous mixing models, underscoring the importance of model treatment. Absorption attribution using the Bruggeman mixing Mie model suggests a minor BrC contribution of 4 % at 530 nm, while its removal would triple the BrC contribution to the total absorption at 470 nm obtained using the AAE (absorption Angstrom exponent) attribution method. Thus, it is recommended that the application of any optical properties-based attribution method use absorption coefficients at the longest possible wavelength to minimize the influence of BrC and to account for potential contributions from other absorbing materials.

COPERNICUS GESELLSCHAFT MBH2022