Publications related to Aluminium hydride

Enantioselective Total Synthesis of (+)-Stephadiamine

Qian Wang, Jieping Zhu, Baochao Yang, Guang Li

An asymmetric synthesis of (+)-stephadiamine has been accomplished featuring (a) an enantioselective dearomatizative Michael addition to generate a quaternary stereocenter; (b) a domino sequence involving reductive generation of nitrone from γ-nitro ketone ...

2023

Decarbonizing The Production of Primary Aluminium Using Renewable Resource

Aluminium is the second most widely used metal in the world, with a variety of applications ranging from transportation to food packaging and construction. While many aluminium producers target increased utilization of recycled aluminium to produce rolled ...

Orlando, FL, American Institute of Chemical Engineering2023

Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets

Andreas Züttel, Emad Oveisi, Heena Yang, Mo Li, Youngdon Ko

Supported aluminum-based complex hydrides (alanates) were investigated in view of their interaction at the interface. Nickel-containing porous carbon sheets (Ni-PCSs) were combined with various alanates, resulting in a decrease of the decomposition tempera ...

AMER CHEMICAL SOC2020

Palladium Catalysed Intramolecular Carbo-oxygenation of Propargylic Amines to Access 1,2-Amino Alcohols and alpha-Amino Ketones via in situ Tether Formation

Phillip Gulliver Dominic Greenwood

a-Amino ketones and 1,2-amino alcohols are important structural motifs in organic chemistry, that can be observed in natural products, pharmaceutically and bioactive compounds. For these reasons, they constitute privileged targets for the development of ne ...

EPFL2020

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

Klaus Kern, Anna Maria Roslawska, Abhishek Grewal

The hexagonal close packed surface of gold shows a 22 x root 3 "herringbone" surface reconstruction which makes it unique among the (111) surfaces of all metals. This long-range energetically favored dislocation pattern appears in response to the strong te ...

AMER CHEMICAL SOC2020

A 1,3,2-Diazaphospholene-Catalyzed Reductive Claisen Rearrangement

Nicolai Cramer, Pavel Alexandrovich Donets, John Henry Reed, Solène Florie Miaskiewicz

1,3,2-Diazaphospholenes (DAPs) are an emerging class of organic hydrides. In this work, we exploited them as efficient catalysts for very mild reductive Claisen rearrangements. The method is tolerant towards a wide variety of functional groups and operates ...

2019

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone

Here we show that a scaffold combining siloxide ligands and a bridging oxide allows the synthesis and characterization of the stable dinuclear uranium(IV) hydride complex [K-2{U(OSi((OBu)-Bu-t)(3))(3)(mu-O)(mu-H)(2)}], 2, which displays high reductive ...

2019

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Qian Wang, Jieping Zhu, Wangqing Kong

Pd-catalyzed intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by reduction of C(sp3)-Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3-disubstituted oxindoles in high yields and enantioselectiviti ...

Wiley-Blackwell2017

Modelling the future secondary resource availability and recycling potential of aluminium in austria

Production of secondary aluminium (Al) currently represents about 70% of total European Al production with a still rising trend and about 50% European final Al demand. The utilization of anthropogenic Al resources as secondary raw materials is therefore a ...

A World Resources Forum Production, PSI2017

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Aluminium hydride

Enantioselective Total Synthesis of (+)-Stephadiamine

Decarbonizing The Production of Primary Aluminium Using Renewable Resource

Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets

1,3,2‐Diazaphospholenes Catalyze the Conjugate Reduction of Substituted Acrylic Acids

Palladium Catalysed Intramolecular Carbo-oxygenation of Propargylic Amines to Access 1,2-Amino Alcohols and alpha-Amino Ketones via in situ Tether Formation

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

A 1,3,2-Diazaphospholene-Catalyzed Reductive Claisen Rearrangement

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Modelling the future secondary resource availability and recycling potential of aluminium in austria

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Chat with Graph Search

Palladium Catalysed Intramolecular Carbo-oxygenation of Propargylic Amines to Access 1,2-Amino Alcohols and alpha-Amino Ketones via in situ Tether Formation

Decarbonizing The Production of Primary Aluminium Using Renewable Resource

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

Modelling the future secondary resource availability and recycling potential of aluminium in austria

Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets

1,3,2‐Diazaphospholenes Catalyze the Conjugate Reduction of Substituted Acrylic Acids

Enantioselective Total Synthesis of (+)-Stephadiamine

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

A 1,3,2-Diazaphospholene-Catalyzed Reductive Claisen Rearrangement

CO2 and CO/H-2 Conversion to Methoxide by a Uranium(IV) Hydride