Concept
Ferrocene
Related publications (32)
New Applications of 1,3,2-Diazaphospholenes in Catalysis
The constant urge to construct new molecules in an economical and sustainable fashion led to the development of numerous metal-catalyzed transformations. Organocatalysts consisting of abundant and more sustainable elements offer an elegant solution to over ...
EPFL2024Five-Membered Rings Create Off-Zero Modes in Nanographene
Oleg Yazyev, Kristians Cernevics, Ziyi Wang
The low-energy electronic structure of nanographenes can be tuned through zero-energy pi-electron states, typically referred to as zero-modes. Customizable electronic and magnetic structures have been engineered by coupling zero-modes through exchange and ...
Washington2023Synthesis and Applications of Ynimines and Enantioselective Total Synthesis of Artatrovirenol A
The first chapter of this thesis describe the development of a general synthesis of ynimines, an under-exploited motif in organic chemistry. In the presence of an inexpensive copper catalyst and 2,2'-biquinoline, reaction of easily accessible O-acyloximes ...
EPFL2023Automated approach for the evaluation of glutathione-S-transferase P1-1 inhibition by organometallic anticancer compounds
Paul Joseph Dyson, Sarah Alexandra Pais Pereira
A novel automated method based on sequential injection analysis (SIA), a non-segmented flow injection technique, was developed to evaluate glutathione S-transferase P1-1 (GST P1-1) activity in the presence of organometallic complexes with putative anticanc ...
TAYLOR & FRANCIS LTD2022Mapping Catalyst‐Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions
Nicolai Cramer, Matthew Wodrich, Miyeon Chang, Simone Gallarati
Group 9 metals, in particular Rh III complexes with cyclopentadienyl ligands, are competent C–H activation catalysts. Recently, a Cp*Rh III catalyzed reaction of alkenes with N -enoxyphthalimides showed divergent outcome based on the solvent, with carboami ...
2022Design guidelines for next-generation sodium-nickel-chloride batteries
Sodium-nickel-chloride batteries have a proven track record for backup power applications, but also show great potential for large-scale stationary electricity storage currently dominated by lithium-ion batteries. While lithium-ion cells rely on critical c ...
EPFL2022Synthesis of Chiral Cyclopentadienyl Complexes and Applications Towards C-H Functionalization
Metal-catalysed C-H bond functionalization has received tremendous attention and developed rapidly over the past decades. Cyclopentadienyl (Cp) metal complexes and their asymmetric counterparts (CpX) are part of a central organometallic category empowering ...
EPFL2021Atomic Level Insights of Non-Noble Metal Catalysts for the Oxygen Evolution Reaction
The conversion of intermittent renewable energy resources in the form of chemical bond, such as hydrogen production from electrochemical water splitting, is a promising way to satisfy the future global energy demand and address the environmental issues. Th ...
EPFL2021