Publications related to Metal nitrosyl complex

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Rosario Scopelliti

To investigate the effect of different halogen substituents and leaving groups and the flexibility of ligands on the anticancer activity of copper complexes, sixteen copper(ii) complexes with eight different tridentate Schiff-base ligands containing pyridi ...

ROYAL SOC CHEMISTRY2021

Arene-ruthenium(II) complexes with pyrazole-based ligands bearing a pyridine moiety: Synthesis, structure, DFT calculations, and cytotoxicity

Paul Joseph Dyson, Farzaneh Fadaei Tirani, Mouna Hadiji

Two pyrazole-based ligands bearing a pyridine moiety, 3-methyl-1-(pyridin-2-yl)-5-pyrazolone (HLpy), and 3methyl-1-(pyridin-2-yl)-4-trifluoroacetyl-5-pyrazolone (HQpy,CF3), were prepared and fully characterized in the solid-state and the tautomerism of bot ...

ELSEVIER SCIENCE SA2021

Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Rujin Li

Spherical assemblies of the type [PdnL2n]2n+ can be obtained from PdII salts and curved N-donor ligands, L. It is well established that the bent angle, α, of the ligand is a decisive factor in the self-assembly process, with larger angles leading to comple ...

2021

Azatruxene-Based, Dumbbell-Shaped, Donor-pi-Bridge-Donor Hole-Transporting Materials for Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Cristina Roldán Carmona, Inés Garcia Benito, Cansu Igci, Javier Urieta Mora

Three novel donor-pi-bridge-donor (D-pi-D) hole-transporting materials (HTMs) featuring triazatruxene electron-donating units bridged by different 3,4-ethylenedioxythiophene (EDOT) pi-conjugated linkers have been synthesized, characterized, and implemented ...

2020

A Cobalt-Iron Double-Atom Catalyst for the Oxygen Evolution Reaction

Xile Hu, Duncan Thomas Lindsay Alexander, Lichen Bai

Single-atom catalysts exhibit well-defined active sites and potentially maximum atomic efficiency. However, they are unsuitable for reactions that benefit from bimetallic promotion such as the oxygen evolution reaction (OER) in an alkaline medium. Here we ...

2019

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Marinella Mazzanti, Marta Falcone, Luciano Barluzzi

The synthesis and reactivity of uranium compounds supported by the tris-tert-butoxysiloxide ligand is surveyed. The multiple binding modes of the tert-butoxysiloxide ligand have proven very well suited to stabilize highly reactive homo- and heteropolymetal ...

2019

Double bridged mu(2)-Halide Cu (II) complexes for the electrocatalytic reduction of CO2

Kurt Schenk, Farzaneh Fadaei Tirani, Jun Gu

Two dicopper (II) complexes of general formula CuLX2 {L = 2, 5-diphenyl-3, 4(2-pyridyl) cyclopenta-2, 4-dien-1-one, X = Cl (1) or Br (2)} have been synthesized and characterized by elemental analysis, IR, UV-Vis spectroscopic methods. The crystal stru ...

2019

Synthesis and Characterization of a Water Stable Uranyl(V) Complex

Rosario Scopelliti, Marinella Mazzanti, Anne-Sophie Chauvin, Radmila Faizova

We have identified a polydentate aminocarboxylate ligand that stabilizes uranyl(V) in water. The mononuclear [UO2(dpaea)]X, (dpaeaH2 = Bis(pyridyl-6-methyl-2-carboxylate)-ethylamine; X = CoCp2*+ or X = K(2.2.2.cryptand) complexes have been isolated from an ...

2018

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone, Rory Patrick Kelly

Herein, we report the synthesis and characterisation of the first terminal uranium(V) sulfide and a related UV trithiocarbonate complex supported by sterically demanding tris(tert-butoxy)siloxide ligands. The reaction of the potassium-bound UV imido comple ...

2017

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Metal nitrosyl complex

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Arene-ruthenium(II) complexes with pyrazole-based ligands bearing a pyridine moiety: Synthesis, structure, DFT calculations, and cytotoxicity

Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle

Electrochemical evaluation of iron-binding ligands along the Australian GEOTRACES southwestern Pacific section (GP13)

Azatruxene-Based, Dumbbell-Shaped, Donor-pi-Bridge-Donor Hole-Transporting Materials for Perovskite Solar Cells

A Cobalt-Iron Double-Atom Catalyst for the Oxygen Evolution Reaction

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Double bridged mu(2)-Halide Cu (II) complexes for the electrocatalytic reduction of CO2

Synthesis and Characterization of a Water Stable Uranyl(V) Complex

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

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Electrochemical evaluation of iron-binding ligands along the Australian GEOTRACES southwestern Pacific section (GP13)

Tuning the Size and Geometry of Heteroleptic Coordination Cages by Varying the Ligand Bent Angle

Arene-ruthenium(II) complexes with pyrazole-based ligands bearing a pyridine moiety: Synthesis, structure, DFT calculations, and cytotoxicity

Azatruxene-Based, Dumbbell-Shaped, Donor-pi-Bridge-Donor Hole-Transporting Materials for Perovskite Solar Cells

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

A Cobalt-Iron Double-Atom Catalyst for the Oxygen Evolution Reaction

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Synthesis and Characterization of a Water Stable Uranyl(V) Complex

Double bridged mu(2)-Halide Cu (II) complexes for the electrocatalytic reduction of CO2