A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic CCD for Cathode Current Departs. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. Consequently, the mnemonic cathode current departs also means that electrons flow into the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode.
The electrode through which conventional current flows the other way, into the device, is termed an anode.
Conventional current flows from cathode to anode outside of the cell or device (with electrons moving in the opposite direction), regardless of the cell or device type and operating mode.
Cathode polarity with respect to the anode can be positive or negative depending on how the device is being operated. Inside a device or a cell, positively charged cations always move towards the cathode and negatively charged anions move towards the anode, although cathode polarity depends on the device type, and can even vary according to the operating mode. Whether the cathode is negatively polarized (such as recharging a battery) or positively polarized (such as a battery in use), the cathode will draw electrons into it from outside, as well as attract positively charged cations from inside.
A battery or galvanic cell in use has a cathode that is the positive terminal since that is where conventional current flows out of the device. This outward current is carried internally by positive ions moving from the electrolyte to the positive cathode (chemical energy is responsible for this "uphill" motion). It is continued externally by electrons moving into the battery which constitutes positive current flowing outwards. For example, the Daniell galvanic cell's copper electrode is the positive terminal and the cathode.
This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.
This course builds upon the underlying theory in thermodynamics, reaction kinetics, and transport and applies these methods to electrosynthesis, fuel cell, and battery applications. Special focus is p
Ce cours permet l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimique en liaison avec les propriétés mécaniques, thermiques, électri
The course presents the detection of ionizing radiation in the keV and MeV energy ranges. Physical processes of radiation/matter interaction are introduced. All steps of detection are covered, as well
Delves into concentration cells, solubility products, half-cell potentials, and electrochemical applications, including corrosion prevention and fuel cells.
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery. The electrophore, invented by Johan Wilcke, was an early version of an electrode used to study static electricity. Electrodes are an essential part of any battery. The first electrochemical battery made was devised by Alessandro Volta and was aptly named the Voltaic cell.
An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ACID, for "anode current into device". The direction of conventional current (the flow of positive charges) in a circuit is opposite to the direction of electron flow, so (negatively charged) electrons flow out the anode of a galvanic cell, into an outside or external circuit connected to the cell.
A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric potential difference has been applied. The type known as a thermionic tube or thermionic valve utilizes thermionic emission of electrons from a hot cathode for fundamental electronic functions such as signal amplification and current rectification.
A gas diffusion electrode (GDE) based CO2 electrolyzer shows enhanced CO2 transport to the catalyst surface, significantly increasing current density compared to traditional planar immersed electrodes. A two-dimensional model for the cathode side of a micr ...
Layered cathodes are among the most promising cathodes for high-energy-density Li-ion batteries, yet hindered by the structural degradation from both bulk strain and surface oxygen loss at high voltage (above 4.5 V). Herein, we report a pre-fatigue trainin ...
Cambridge2024
In the field of electrochemical CO2 reduction, both continuum models and molecular dynamics (MD) models have been used to understand the electric double layer (EDL). MD often focuses on the region within a few nm of the electrode, while continuum models ca ...