Internal resistance

In electrical engineering, a practical electric power source which is a linear circuit may, according to Thévenin's theorem, be represented as an ideal voltage source in series with an impedance. This impedance is termed the internal resistance of the source. When the power source delivers current, the measured voltage output is lower than the no-load voltage; the difference is the voltage drop (the product of current and resistance) caused by the internal resistance. The concept of internal resistance applies to all kinds of electrical sources and is useful for analyzing many types of circuits. A battery may be modeled as a voltage source in series with a resistance. These types of models are known as equivalent circuit models. Another common model being physiochemical models that are physical in nature involving concentrations and reaction rates. In practice, the internal resistance of a battery is dependent on its size, state of charge, chemical properties, age, temperature, and the discharge current. It has an electronic component due to the resistivity of the component materials and an ionic component due to electrochemical factors such as electrolyte conductivity, ion mobility, speed of electrochemical reaction and electrode surface area. Measurement of the internal resistance of a battery is a guide to its condition, but may not apply at other than the test conditions. Measurement with an alternating current, typically at a frequency of 1kHz, may underestimate the resistance, as the frequency may be too high to take into account slower electrochemical processes. Internal resistance depends on temperature; for example, a fresh Energizer E91 AA alkaline primary battery drops from about 0.9 Ω at -40 °C, when the low temperature reduces ion mobility, to about 0.15 Ω at room temperature and about 0.1 Ω at 40 °C. A large part of this drop is due to the increase in the magnitude of the electrolyte diffusion coefficient.