The atmosphere of the Moon is a very scant presence of gases surrounding the Moon. For most practical purposes, the Moon is considered to be surrounded by vacuum. The elevated presence of atomic and molecular particles in its vicinity compared to interplanetary medium, referred to as "lunar atmosphere" for scientific objectives, is negligible in comparison with the gaseous envelopes surrounding Earth and most planets of the Solar System. The pressure of this small mass is around , varying throughout the day, and in total mass less than 10 metric tonnes. Otherwise, the Moon is considered not to have an atmosphere because it cannot absorb measurable quantities of radiation, does not appear layered or self-circulating, and requires constant replenishment due to the high rate at which its gases get lost into space.
Roger Joseph Boscovich was the first modern astronomer to argue for the lack of atmosphere around the Moon in his De lunae atmosphaera (1753).
One source of the lunar atmosphere is outgassing: the release of gases such as radon and helium resulting from radioactive decay within the crust and mantle. Another important source is the bombardment of the lunar surface by micrometeorites, the solar wind, and sunlight, in a process known as sputtering.
Gases can:
be re-implanted into the regolith as a result of the Moon's gravity;
escape the Moon entirely if the particle is moving at or above the lunar escape velocity of , or ;
be lost to space either by solar radiation pressure or, if the gases are ionized, by being swept away in the solar wind's magnetic field.
What little atmosphere the Moon has consists of some unusual gases, including sodium and potassium, which are not found in the atmospheres of Earth, Mars, or Venus. At sea level on Earth, each cubic centimeter of the atmosphere contains approximately molecules; by comparison the lunar atmosphere contains fewer than molecules in the same volume. On Earth, this is considered to be a very good vacuum.
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