Concept

Transition state theory

Related publications (207)

Stark coefficients for highly excited rovibrational states of H2O

Thomas Rizzo, Oleg Boyarkine, Maxim Grechko, Oleg Aseev

Quantum beat spectroscopy is combined with triple-resonance vibrational overtone excitation to measure the Stark coefficients (SCs) of the water molecule for 28 rovibrational levels lying from 27 600 to 41 000 cm−1. These data provide a stringent test for ...

American Institute of Physics2012

O-17 NMR and Density Functional Theory Study of the Dynamics of the Carboxylate Groups in DOTA Complexes of Lanthanides in Aqueous Solution

Lothar Helm

The rotation of the carboxylate groups in DOTA (DOTA = 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetate) complexes of several lanthanide ions and Sc3+ was investigated with density functional theory (DFT) calculations and with variable temperature O-17 ...

2012

Measurement of gamma gamma* -> pi(0) transition form factor at Belle

Olivier Schneider, Yiming Li, Chao Wang, Tagir Aushev, Jun Yong Kim, Remi Léandre Albert Louvot, Ji Hyun Kim, Jing Li

We report a measurement of the process gamma gamma* -> pi(0) with a 759 fb(-1) data sample recorded with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. The pion transition form factor, F(Q(2)), is measured for the kinematical region 4 ...

Amer Physical Soc2012

Massively parallel measurements of molecular interaction kinetics on a microfluidic platform

Sebastian Maerkl, Marcel Geertz

Quantitative biology requires quantitative data. No high-throughput technologies exist capable of obtaining several hundred independent kinetic binding measurements in a single experiment. We present an integrated microfluidic device (k-MITOMI) for the sim ...

Natl Acad Sciences2012

Comparison of measured and calculated reaction rate distributions in an scwr-like test lattice

Rakesh Chawla

High resolution gamma-ray spectroscopy measurements were performed on 61 rods of an SCWR-like fuel lattice, after irradiation in the central test zone of the PROTEUS zero-power research reactor at the Paul Scherrer Institute in Switzerland. The derived rea ...

Elsevier2011

On measured activation volumes as relevant to ratcheting or cyclic creep

Andreas Mortensen, Sébastien Philippe Soubielle

We consider a material having a constant true activation volume and estimate the apparent activation volume that it displays in cyclic creep or ratcheting. We show that cyclic stresses have an effect on the measured value, and that this can be accounted fo ...

Elsevier2011

About the activation volume for cross-slip in Cu at high stresses

Jean-Luc Martin

The experiment performed by Bonneville and Escaig, designed for the direct measurement of the activation parameters of cross-slip, has been repeated. A denser initial dislocation forest density is obtained with a higher predeformation stress compared with ...

2011

Evaporation kinetics of volatile liquids and release kinetics of water from a smectite clay: Comparison between experiments and finite element calculations

John Christopher Plummer, Pascal Clausen

Numerical calculations of the evaporation kinetics of bulk volatile liquids and of water from smectite clay granules are compared with experimental results. The weight loss of the volatiles is analyzed by thermogravimetry and differential calorimetry. Unde ...

2011

Experimental validation of control rod related perturbations of moderator regions in an SCWR-like fuel lattice

Rakesh Chawla

Two different types of perturbations of an SCWR-like fuel lattice have been investigated experimentally in the central test zone of the PROTEUS zero-power research reactor at the Paul Scherrer Institute in Switzerland. In each case, a campaign of high-reso ...

Elsevier2011

Size-resolved CCN distributions and activation kinetics of aged continental and marine aerosol

Athanasios Nenes, Spyros Pandis

We present size-segregated measurements of cloud condensation nucleus (CCN) activity of aged aerosol sampled at Finokalia, Crete, during the Finokalia Aerosol Measurement Experiment of summer 2007 (FAME07). From analysis of the data, hygroscopicity and act ...

2011

Graph Chatbot

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.