Letter caseLetter case is the distinction between the letters that are in larger uppercase or capitals (or more formally majuscule) and smaller lowercase (or more formally minuscule) in the written representation of certain languages. The writing systems that distinguish between the upper- and lowercase have two parallel sets of letters: each in the majuscule set has a counterpart in the minuscule set. Some counterpart letters have the same shape, and differ only in size (e.g. {C,c} or {S,s}), but for others the shapes are different (e.
HH, or h, is the eighth letter in the Latin alphabet, used in the modern English alphabet, including the alphabets of other western European languages and others worldwide. Its name in English is aitch (pronounced eɪtʃ, plural aitches), or regionally haitch heɪtʃ. The original Semitic letter Heth most likely represented the voiceless pharyngeal fricative (ħ). The form of the letter probably stood for a fence or posts. The Greek Eta 'Η' in archaic Greek alphabets, before coming to represent a long vowel, /ɛː/, still represented a similar sound, the voiceless glottal fricative /h/.
Rearrangement reactionIn organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below, the substituent R moves from carbon atom 1 to carbon atom 2: Intermolecular rearrangements also take place.
Claisen rearrangementThe Claisen rearrangement is a powerful carbon–carbon bond-forming chemical reaction discovered by Rainer Ludwig Claisen. The heating of an allyl vinyl ether will initiate a [3,3]-sigmatropic rearrangement to give a γ,δ-unsaturated carbonyl, driven by exergonically favored carbonyl CO bond formation (ΔΔHf = -327 kcal·mol−1). The Claisen rearrangement is an exothermic, concerted (bond cleavage and recombination) pericyclic reaction. Woodward–Hoffmann rules show a suprafacial, stereospecific reaction pathway.
H-droppingH-dropping or aitch-dropping is the deletion of the voiceless glottal fricative or "H-sound", [h]. The phenomenon is common in many dialects of English, and is also found in certain other languages, either as a purely historical development or as a contemporary difference between dialects. Although common in most regions of England and in some other English-speaking countries, and linguistically speaking a neutral evolution in languages, H-dropping is often stigmatized as a sign of careless or uneducated speech.
