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This lecture explores the sustainable materials derived from biopolymers, focusing on the structures and properties of biopolymeric constructs at different scales. Topics include the scaling down of cellulosic building blocks, the comparison between native and regenerated cellulose crystals, and the impact of deconstruction on fabricated materials. The lecture also delves into the transfer of properties from nano- to macroscale, the societal impact of biopolymeric materials, and the scientific and societal collaborations in the field.