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This lecture covers the second law of thermodynamics, starting with a brief introduction and a comparison with the first law. The concepts of Clausius and Kelvin-Planck statements are discussed, showing their equivalence. Examples of heat engines are provided to illustrate the principles. The lecture explains the historical development of the second law, its practical implications in optimizing thermal engines, and its philosophical consequences related to entropy and the arrow of time. The limitations on the efficiency of heat engines are explored through the statements of Clausius and Kelvin, demonstrating their equivalence and the necessity of high and low-temperature heat reservoirs for engine operation.