This lecture discusses the interactions between electromagnetic radiation (EMR) and the Earth's surface and atmosphere. It begins with the principles of refraction and reflection, including Snell's law and Brewster's law, which describe how light behaves at the interface of different media. The instructor explains the significance of surface roughness in determining the type of reflection, distinguishing between specular and diffuse reflection based on the wavelength of the incident light. The Bidirectional Reflectance Distribution Function (BRDF) is introduced as a method to quantify reflected radiation based on incident angles. The lecture emphasizes the importance of solar radiation in environmental processes and the energy balance at the Earth's surface, detailing how net radiation is calculated and its implications for climate and energy exchanges. The discussion extends to the spectral signatures of various surfaces, including soil, vegetation, and water, highlighting how these signatures can be used in remote sensing applications. The lecture concludes with a focus on the spectral response of different materials and their relevance in environmental monitoring.