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Barnali Dutta

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Related publications (8)

Please note that this is not a complete list of this person’s publications. It includes only semantically relevant works. For a full list, please refer to Infoscience.

Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp^RuCl2](2) ("Cp-roof" = eta(5)-1-Methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl)

Rosario Scopelliti, Kay Severin, Euro Solari, Barnali Dutta, Julie Risse

The dimeric ruthenium complex Cp^RuCl2 is easily accessible in a one-pot reaction from RuCl3(solv)(n) and tert-butylacetylene. It features sterically very demanding "Cp-roof" ligands (Cp^ = eta(5)-1-methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl), ...

Wiley-Blackwell2014

RhCl3-Mediated Coupling Reactions of tert-Butyl Acetylene

Rosario Scopelliti, Kay Severin, Euro Solari, Gregor Kiefer, Barnali Dutta

RhCl3 is shown to mediate unusual coupling reactions of tert-butyl acetylene. When RhCl3(H2O)n was heated with four equivalents of tert-butyl acetylene in methanol, the dinuclear complex [{Rh(μ-Cl)(CH2tBu)(tBuC=CHCOCH2tBu)}2] (2) was isolated. A larger exc ...

Wiley-Blackwell2012

Reactions of Alkynes with [RuCl(cyclopentadienyl)] Complexes: The Important First Steps

Rosario Scopelliti, Ursula Röthlisberger, Kay Severin, Euro Solari, Basile Curchod, Pablo Campomanes Ramos, Barnali Dutta

Cyclopentadienyl-ruthenium half-sandwich complexes with 2-bound alkyne ligands have been suggested as catalytic intermediates in the early stages of Ru-catalyzed reactions with alkynes. We show that electronically unsaturated complexes of the formula [RuCl ...

2010