Farzaneh Fadaei Tirani

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New melphalan derivatives for the treatment of retinoblastoma in combination with thermotherapy

Paul Joseph Dyson, Farzaneh Fadaei Tirani, Aurélien Bornet, Daniel Ortiz Trujillo

Of the different modalities used to treat retinoblastoma, a chemothermotherapeutic regimen combining carboplatin and thermotherapy (also termed focal therapy), and the application of melphalan as a monotherapy, are particularly successful. Some studies ind ...

Royal Soc Chemistry2024

Dopant-Free Pyrene-Based Hole Transporting Material Enables Efficient and Stable Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Farzaneh Fadaei Tirani, Yong Ding, Bin Ding, Keith Gregory Brooks

Dopant-free hole transporting materials (HTMs) is significant to the stability of perovskite solar cells (PSCs). Here, we developed a novel star-shape arylamine HTM, termed Py-DB, with a pyrene core and carbon-carbon double bonds as the bridge units. Compa ...

Wiley-VCH Verlag GmbH2024

Nano onions based on an amphiphilic Au3(pyrazolate)3 complex

Kay Severin, Farzaneh Fadaei Tirani, Atena-Bianca Solea

Multilayer vesicles with an onion-like architecture can form by self-assembly of organic amphiphiles such as dendrimers, small-molecule surfactants, and block copolymers. Thus far, there are limited reports about multilayer vesicles based on coordination c ...

ROYAL SOC CHEMISTRY2024

Enantiospecific Synthesis of Planar Chiral Rhodium and Iridium Cyclopentadienyl Complexes: Enabling Streamlined and Computer-Guided Access to Highly Selective Catalysts for Asymmetric C-H Functionalizations

Rosario Scopelliti, Nicolai Cramer, Farzaneh Fadaei Tirani, Matthew Wodrich, Rubén Laplaza Solanas, Anne-Clémence Corminboeuf, Aragorn Nathan Laverny

Chiral cyclopentadienyl (CpX) metal complexes are frequently used in asymmetric catalysis by virtue of their high reactivity and selectivity. Planar-chiral-only rhodium and iridium cyclopentadienyl complexes are particularly promising due to unrestricted c ...

2024

Stepwise synthesis of heterotrimetallic FeII/PdII/AuI coordination cages

Kay Severin, Farzaneh Fadaei Tirani, Noga Eren

The synthesis of heterotrimetallic molecular cages is reported. The assemblies contain three types of coordination compounds: FeII clathrochelate complexes, AuI3(pyrazolate)3 complexes, and [PdII(pyridine)4]2+ complexes. The cages were obtained in a stepwi ...

2024

A score and nine years of irbesartan

Farzaneh Fadaei Tirani

Irbesartan is a non-peptide antagonist of the angiotensin-II-AT1 receptor and is used for the treatment of hypertension. Here, the history, achievements and open questions related to irbesartan are examined. Tautomery of the tetrazole moiety leads to two d ...

2024

Orientational Self-Sorting in Octahedral Palladium Cages: Scope and Limitations of the “cis Rule”

Kay Severin, Farzaneh Fadaei Tirani, Damien Wen Chen, Jean Charles Edouard de Montmollin, Atena-Bianca Solea

Octahedral coordination cages of the general formula Pd6L1212 were obtained by combining Pd(CH3CN)42 with heteroditopic N-donor ligands. Four different ligands were employed. These ligands have 3-pyridyl donor groups at one end and 4-pyridyl, ...

2024

A trinuclear metallasilsesquioxane of uranium(III)

Rosario Scopelliti, Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Nadir Jori

The silsesquioxane ligand (Bu-i)(7)Si7O9(OH)(3) ((POSSH3)-P-iBu) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U-3((POSS) ...

Royal Society of Chemistry2024

Molecular imine cages with π-basic Au3(pyrazolate) faces

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Noga Eren

One tetrahedral and two trigonal prismatic cages with π-basic Au3(pyrazolate)3 faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au3(pyrazolate)3 complexes in the prismatic ...

2024

Shallow-level defect passivation by 6H perovskite polytype for highly efficient and stable perovskite solar cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Farzaneh Fadaei Tirani, Pascal Alexander Schouwink, Yong Ding, Hiroyuki Kanda, Hobeom Kim, So-Min Yoo

The power conversion efficiency of perovskite solar cells continues to increase. However, defects in perovskite materials are detrimental to their carrier dynamics and structural stability, ultimately limiting the photovoltaic characteristics and stability ...

Nature Research2024

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Enantiospecific Synthesis of Planar Chiral Rhodium and Iridium Cyclopentadienyl Complexes: Enabling Streamlined and Computer-Guided Access to Highly Selective Catalysts for Asymmetric C-H Functionalizations

Rosario Scopelliti, Nicolai Cramer, Farzaneh Fadaei Tirani, Matthew Wodrich, Rubén Laplaza Solanas, Anne-Clémence Corminboeuf, Aragorn Nathan Laverny

2024