Hamiltonian (quantum mechanics)In quantum mechanics, the Hamiltonian of a system is an operator corresponding to the total energy of that system, including both kinetic energy and potential energy. Its spectrum, the system's energy spectrum or its set of energy eigenvalues, is the set of possible outcomes obtainable from a measurement of the system's total energy. Due to its close relation to the energy spectrum and time-evolution of a system, it is of fundamental importance in most formulations of quantum theory.
Kinetic isotope effectIn physical organic chemistry, a kinetic isotope effect (KIE) is the change in the reaction rate of a chemical reaction when one of the atoms in the reactants is replaced by one of its isotopes. Formally, it is the ratio of rate constants for the reactions involving the light (kL) and the heavy (kH) isotopically substituted reactants (isotopologues): This change in reaction rate is a quantum mechanical effect that primarily results from heavier isotopologues having lower vibrational frequencies compared to their lighter counterparts.
Isobaric processIn thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the system stays constant: ΔP = 0. The heat transferred to the system does work, but also changes the internal energy (U) of the system. This article uses the physics sign convention for work, where positive work is work done by the system. Using this convention, by the first law of thermodynamics, where W is work, U is internal energy, and Q is heat.
Reactive armourReactive armour is a type of vehicle armour that reacts in some way to the impact of a weapon to reduce the damage done to the vehicle being protected. It is most effective in protecting against shaped charges and specially hardened kinetic energy penetrators. The most common type is explosive reactive armour (ERA), but variants include self-limiting explosive reactive armour (SLERA), non-energetic reactive armour (NERA), non-explosive reactive armour (NxRA), and electric armour.
Euclidean relationIn mathematics, Euclidean relations are a class of binary relations that formalize "Axiom 1" in Euclid's Elements: "Magnitudes which are equal to the same are equal to each other." A binary relation R on a set X is Euclidean (sometimes called right Euclidean) if it satisfies the following: for every a, b, c in X, if a is related to b and c, then b is related to c.
Transitive relationIn mathematics, a relation R on a set X is transitive if, for all elements a, b, c in X, whenever R relates a to b and b to c, then R also relates a to c. Each partial order as well as each equivalence relation needs to be transitive. A homogeneous relation R on the set X is a transitive relation if, for all a, b, c ∈ X, if a R b and b R c, then a R c. Or in terms of first-order logic: where a R b is the infix notation for (a, b) ∈ R. As a non-mathematical example, the relation "is an ancestor of" is transitive.
