Synthetic process development and scale up of palladium-catalyzed alkoxycarbonylation of chloropyridines
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The solubility of carbon monoxide in 37 ionic liquids and in some organic solvents has been determined using high-pressure C-13 NMR spectroscopy; a method for predicting the CO solubility is demonstrated, and it was shown that the rate of the hydroformylat ...
Current UML based behavioral requirements focus on the specification of use cases. Business rules are seen as a very important part of the requirements but are either considered as a separate entity or, at best, attached to use cases. Some authors have rec ...
The aim of this work was to operate the steam reforming of methanol and the total oxidation of methanol in a microstructured two-passage reactor. The steam reforming enables the production of hydrogen at relatively low temperatures (250 °C) with only a sma ...
The Web services resource framework (WS-RF) and the Web services notification (WS-N) specifications are a crucial component of grid infrastructures. They provide a standardized interface to stateful services so that they can be managed remotely. There are ...
[Pt-3(mu-CO)(3)(PPh3)(3)] was prepared in high yield by the reaction of [Pt-3(mu-CO)(3)(PPh3)(4)] with H2O2. The carbonyl ligands in [Pt-3(mu-CO)(3)(PR3)(3)] (PR3 = PPh3, PPh(2)Bz, PCy3, P'Pr-3) may be completely replaced by sulfur dioxide to give [Pt-3(mu ...
We have developed a new process for reversing the nanostencil patterns by using an intermediate sacrificial layer. Using this process, we can pattern isolated ‘empty’ shapes with their background filled with a certain material, which is impossible with the ...
Sulphur dioxide reacts with 1-oxydienes generating zwitterions which are quenched by enoxysilanes to form substituted silyl alkenylsulfinates. These intermediates are desilylated with Bu4NF and the resulting sulfinates react with MeI giving the correspondi ...
[Pt-3(mu-CO)(3)(PPh3)(3)] was prepared in high yield by the reaction of [Pt-3(mu-CO)(3)(PPh3)(4)] with H2O2. The carbonyl ligands in [Pt-3(mu-CO)(3)(PR3)(3)] (PR3 = PPh3, PPh(2)Bz, PCy3, P'Pr-3) may be completely replaced by sulfur dioxide to give [Pt-3(mu ...
This work covers homogeneous and biphasic catalysis in ionic liquids and water. The work presented herein is divided into two major parts: catalytic hydrogenation and catalytic hydroformylation. The first part also serves as an introduction to catalysis in ...
The incorporation of carbon into the carbon monoxide and cyanide ligands of [NiFe]-hydrogenases has been investigated by using (13)C labelling in infrared studies of the Allochromatium vinosum enzyme and by (14)C labelling experiments with overproduced Hyp ...