Synthesis of poly(PEGA) Bioconjugates using RAFT Polymerization
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Stimuli-responsive polymers have the unique property of undergoing a reversible phase transition. This property has attracted much interest for their application in the field of medicine and biotechnology, such as drug delivery systems. Linear polymers of ...
A meso-tetraaryl ruthenium porphyrin complex having four polymerizable vinylbenzoxy groups (2) has been synthesized by reaction of pyrrole with 4-(vinylbenzoxy)benzaldehyde and subsequent metalation with [Ru-3(CO)(12)]. The porphyrin complex was immobilize ...
Despite progress during the last decade, the behavior of charged macromolecules, polyelectrolytes, including their interactions is not yet completely understood. In particular, interactions with oppositely charged surfaces, which play a significant role in ...
Recent advances in the fields of biotechnology and medicine have intensified the necessity for pharmaceutical-grade biomacromolecules purification (e.g. enzymes, antibodies, plasmid DNA). One of the key factors for a successful downstream process is the po ...
The influence of the primary molecular parameters chain configuration, architecture and molecular weight (MW) on the mode of mechanical breakdown is discussed for two series of (amorphous) thermoplastic polymers, methyl methacrylate glutarimide copolymers ...
Poly(vinylbenzylammonium chloride) (PVBAC) polyelectrolytes possessing defined chain lengths, narrow chain length distributions, uniform charge d., but substituents of different hydrophilicity and size at the quaternary ammonium group were used as model co ...
A family of cationic polyelectrolytes possessing defined chain lengths, narrow chain length distributions, uniform charge d., but substituents of different hydrophilicity at the quaternary ammonium group served as model compds. for adsorption studies. Thes ...
Fully synthetic polymers were used for the prepn. of hydrogel beads and capsules, in a processing scheme that, originally designed for calcium alginate, was adapted to a "tandem" process, that is the combination a phys. gelation with a chem. crosslinking ...
The scale-up/-down of polymn. reactors has to deal with large viscosity changes during the process, addressing mass- and heat-transfer issues. A practical example on scale-up of styrene and Me methacrylate free radical bulk and soln. polymn. is presented. ...
Pure and K-doped vanadia/titania catalysts have been studied by transient response method and in situ DRIFTS during toluene partial oxidn. They were characterized by FT-Raman spectroscopy, TPR, TPD of pyridine and XPS. In order to elucidate the role of dif ...