Ni-Catalyzed Sonogashira Coupling of Non-activated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides
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The invention concerns the introduction of a coupling group to 6-O-Alkylguanine DNA alkyltransferase from a 6-O-Alkylguanine-coupling group deriv. that enables the immobilization of the enzyme for subsequent anal. The coupling group is bound covalently to ...
Imidazolium- and pyridinium-based ionic liqs. with ether/polyether substituents have been evaluated as solvents for palladium-catalyzed Suzuki C-C coupling reactions. In general, reactions proceed more efficiently in these solvents compared to other ionic ...
Brillouin scattering from transverse-acoustic modes of SrTiO3 is observed, while the frequencies of the soft polar modes are remeasured with hyper-Raman scattering. It is shown that an anomalous decrease of sound velocities at low temperatures results from ...
H2C:CHCH2OR (R = tetrahydropyranyl) gave a mixt. of H2C:CHCHR1OH and R1CHCH2CHO after metalation and reaction with an electrophilic agent R1X, whereas metalation of MeCH:CHOR (R = tetrahydropyranyl) with EtCHMeLi, followed by reaction with MeI and acid hyd ...
tual control method, recently introduced to approximate elliptic and parabolic problems by overlapping domain decompositions, is proposed here for heterogeneous problems. Precisely, we address the coupling of an advection equation with a diffusion-advectio ...
This article presents the design of the inductive links of remotely powered wireless cortical implants for minimum interference from the power link to the data link. This interference is minimized by changing the orientation of the inductors. Different ori ...
Alkylation of alpha -isocyanoacetamide with alkyl halide in MeCN at 0 DegC in the presence of cesium hydroxide afforded the mono-alkylated product in good to excellent yield. [on SciFinder (R)] ...
A series of relatively low-cost ionic liquids, based on the N-butyronitrile pyridinium cation C(3)CNpy, designed to improve catalyst retention, have been prepared and evaluated in Suzuki and Stille coupling reactions. Depending on the nature of the an ...