First-principles theory of infrared absorption spectra at surfaces and interfaces: Application to the Si(100): H2O surface
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Dimethylaminonitrene complexes of IMesM+ (IMes = 1,3-bis(2,4,6-trimethylphenyl)- imidazol-2-ylidene; M = Cu, Ag, Au) were prepared in the gas phase and structurally characterized by high-resolution infrared spectroscopy of the cold species, ion-molecule re ...
Using a density-functional framework, we investigate the vibrational spectra of vitreous SiO2 to determine to what extent these spectra provide information about the medium-range structure of the oxide network. We carry out a comparative study involving th ...
In the pharmaceutical industry, batch crystallization processes at production scale are not always well understood. Several factors have a significant impact on the process of crystallization, such as the physicochemical properties (solubility curve and su ...
The realization of a vertically moving micromirror using electrostatic actuation in a comb drive configuration is presented. The micromirror is designed for the use in tunable mid-infrared Resonant Cavity Enhanced Detectors (RCEDs). It can be displaced mor ...
We report a study on the interaction of the extracellular domain of trans-membrane proteins N-cadherin and Ll with nitrilotriacetic acid (NTA)-terminated self-assembled monolayers (SAMs) grown on silver and gold surfaces. Quartz crystal microbalance (QCM) ...
Wavelength tunable emitters and detectors in the mid-IR wavelength region allow applications including thermal imaging and gas spectroscopy. One way to realize such tunable devices is by using a resonant cavity. By mechanically changing the cavity length w ...
Short interaction lengths limit the application of infrared absorption spectroscopy to the study monolayer thickness films. We employ periodic infrared antenna arrays to obtain 10(4)-10(5) enhancement of protein absorption signals corresponding to zepto-mo ...
Kinetic hard-modelling is often the method of choice in order to determine kinetic parameters of reactions by non-linear optimisation and fitting of measured data. In spectroscopy, kinetic hard-modelling allows decomposing time and wavelength resolved data ...
Wavelength tunable emitters and detectors in the mid-IR wavelength region allow applications including thermal imaging and spectroscopy. Such devices may be realized using a resonant cavity. By mechanically changing the cavity length with MEMS mirror techn ...
Perfectly diffuse light is a fundamental assumption in the Kubelka-Munk (KM) modeL This assumption is, however seldom fulfilled by real media. In this work, we build a bridge between a weakly absorbing medium with an imperfectly diffuse light distribution ...