Crystal field and low energy excitations measured by high resolution RIXS at the L-3 edge of Cu, Ni and Mn
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We present a study of the resonant inelastic scattering response of YbInCu4 excited at the tender YbM5 x-ray edge. In the high-temperature, paramagnetic phase, we observe a multiplet structure which can be understood at an ionic level. Upon cooling through ...
In this thesis I study the synthesis and basic physical properties characterization on 3d, 4d and 5d transition metal compounds. Great success has been obtained in 3d transition metal compounds, in which the electric states are well localized due t ...
CONSPECTUS: The properties of transition metal complexes are interesting not only for their potential applications in solar energy conversion, OLEDs, molecular electronics, biology, photochemistry, etc. but also for their fascinating photophysical properti ...
Transition metal compounds represent a unique class of solids characterized by a surprising richness of physical properties. They display many phenomena and represent the main area of interest for the research on strongly correlated materials. Many novel i ...
In materials where electrons interact strongly, a number of exotic and exciting phenomena arise. The mechanisms at the base of many of these phenomena remain debated, as strongly correlated electron physics represents one of the biggest challenges for mode ...
Collective magnetic excitations are a fascinating aspect of condensed matter physics, where neutron scattering can provide valuable insight into the magnetic properties of physical realisations of model systems. This thesis focuses on the excitation spectr ...
High-resolution powder x-ray diffraction and single-crystal neutron diffraction were used to investigate the crystal structure and magnetic ordering of the compound Pr1-xCax VO3 (0
Understanding and controlling the electronic structure of thin layers of quantum materials is a crucial first step towards designing heterostructures where new phases and phenomena, including the metal-insulator transition (MIT), emerge. Here, we demonstra ...
This thesis is dedicated to the study of various aspects of the electronic structure of two-dimensional transition metal dichalcogenides (TMDs) of chemical composition MX2 (where M is a transition metal atom and X= S, Se, Te), using a combination of \te ...
We present a systematic study of the crystal-field interactions in the LiRF4 (R = Gd, Ho, Er, Tm, and Yb) family of rare-earth magnets. Using detailed inelastic neutron scattering measurements, we have been able to quantify the transition energies and wave ...