Reaction rate constantIn chemical kinetics, a reaction rate constant or reaction rate coefficient (k) is a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants. For a reaction between reactants A and B to form a product C, where A and B are reactants C is a product a, b, and c are stoichiometric coefficients, the reaction rate is often found to have the form: Here k is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution.
Expression (mathematics)In mathematics, an expression or mathematical expression is a finite combination of symbols that is well-formed according to rules that depend on the context. Mathematical symbols can designate numbers (constants), variables, operations, functions, brackets, punctuation, and grouping to help determine order of operations and other aspects of logical syntax. Many authors distinguish an expression from a formula, the former denoting a mathematical object, and the latter denoting a statement about mathematical objects.
Cartan connectionIn the mathematical field of differential geometry, a Cartan connection is a flexible generalization of the notion of an affine connection. It may also be regarded as a specialization of the general concept of a principal connection, in which the geometry of the principal bundle is tied to the geometry of the base manifold using a solder form. Cartan connections describe the geometry of manifolds modelled on homogeneous spaces. The theory of Cartan connections was developed by Élie Cartan, as part of (and a way of formulating) his method of moving frames (repère mobile).
Algebraic expressionIn mathematics, an algebraic expression is an expression built up from constant algebraic numbers, variables, and the algebraic operations (addition, subtraction, multiplication, division and exponentiation by an exponent that is a rational number). For example, 3x2 − 2xy + c is an algebraic expression. Since taking the square root is the same as raising to the power 1/2, the following is also an algebraic expression: An algebraic equation is an equation involving only algebraic expressions.
Rate-determining stepIn chemical kinetics, the overall rate of a reaction is often approximately determined by the slowest step, known as the rate-determining step (RDS or RD-step or r/d step) or rate-limiting step. For a given reaction mechanism, the prediction of the corresponding rate equation (for comparison with the experimental rate law) is often simplified by using this approximation of the rate-determining step. In principle, the time evolution of the reactant and product concentrations can be determined from the set of simultaneous rate equations for the individual steps of the mechanism, one for each step.
Well-formed formulaIn mathematical logic, propositional logic and predicate logic, a well-formed formula, abbreviated WFF or wff, often simply formula, is a finite sequence of symbols from a given alphabet that is part of a formal language. A formal language can be identified with the set of formulas in the language. A formula is a syntactic object that can be given a semantic meaning by means of an interpretation. Two key uses of formulas are in propositional logic and predicate logic.
