Ligand field theoryLigand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes. It represents an application of molecular orbital theory to transition metal complexes. A transition metal ion has nine valence atomic orbitals - consisting of five nd, one (n+1)s, and three (n+1)p orbitals. These orbitals are of appropriate energy to form bonding interaction with ligands. The LFT analysis is highly dependent on the geometry of the complex, but most explanations begin by describing octahedral complexes, where six ligands coordinate to the metal.
Supersymmetric quantum mechanicsIn theoretical physics, supersymmetric quantum mechanics is an area of research where supersymmetry are applied to the simpler setting of plain quantum mechanics, rather than quantum field theory. Supersymmetric quantum mechanics has found applications outside of high-energy physics, such as providing new methods to solve quantum mechanical problems, providing useful extensions to the WKB approximation, and statistical mechanics.
SupersymmetryIn a supersymmetric theory the equations for force and the equations for matter are identical. In theoretical and mathematical physics, any theory with this property has the principle of supersymmetry (SUSY). Dozens of supersymmetric theories exist. Supersymmetry is a spacetime symmetry between two basic classes of particles: bosons, which have an integer-valued spin and follow Bose–Einstein statistics, and fermions, which have a half-integer-valued spin and follow Fermi–Dirac statistics.
Gauge covariant derivativeIn physics, the gauge covariant derivative is a means of expressing how fields vary from place to place, in a way that respects how the coordinate systems used to describe a physical phenomenon can themselves change from place to place. The gauge covariant derivative is used in many areas of physics, including quantum field theory and fluid dynamics and in a very special way general relativity. If a physical theory is independent of the choice of local frames, the group of local frame changes, the gauge transformations, act on the fields in the theory while leaving unchanged the physical content of the theory.
Gauge fixingIn the physics of gauge theories, gauge fixing (also called choosing a gauge) denotes a mathematical procedure for coping with redundant degrees of freedom in field variables. By definition, a gauge theory represents each physically distinct configuration of the system as an equivalence class of detailed local field configurations. Any two detailed configurations in the same equivalence class are related by a gauge transformation, equivalent to a shear along unphysical axes in configuration space.
Superstring theorySuperstring theory is an attempt to explain all of the particles and fundamental forces of nature in one theory by modeling them as vibrations of tiny supersymmetric strings. 'Superstring theory' is a shorthand for supersymmetric string theory because unlike bosonic string theory, it is the version of string theory that accounts for both fermions and bosons and incorporates supersymmetry to model gravity. Since the second superstring revolution, the five superstring theories (Type I, Type IIA, Type IIB, HO and HE) are regarded as different limits of a single theory tentatively called M-theory.
SupergravityIn theoretical physics, supergravity (supergravity theory; SUGRA for short) is a modern field theory that combines the principles of supersymmetry and general relativity; this is in contrast to non-gravitational supersymmetric theories such as the Minimal Supersymmetric Standard Model. Supergravity is the gauge theory of local supersymmetry. Since the supersymmetry (SUSY) generators form together with the Poincaré algebra a superalgebra, called the super-Poincaré algebra, supersymmetry as a gauge theory makes gravity arise in a natural way.
Inflation (cosmology)In physical cosmology, cosmic inflation, cosmological inflation, or just inflation, is a theory of exponential expansion of space in the early universe. The inflationary epoch is believed to have lasted from seconds to between and seconds after the Big Bang. Following the inflationary period, the universe continued to expand, but at a slower rate. The acceleration of this expansion due to dark energy began after the universe was already over 7.7 billion years old (5.4 billion years ago).
History of quantum field theoryIn particle physics, the history of quantum field theory starts with its creation by Paul Dirac, when he attempted to quantize the electromagnetic field in the late 1920s. Heisenberg was awarded the 1932 Nobel Prize in Physics "for the creation of quantum mechanics". Major advances in the theory were made in the 1940s and 1950s, leading to the introduction of renormalized quantum electrodynamics (QED). QED was so successful and accurately predictive that efforts were made to apply the same basic concepts for the other forces of nature.
OrbifoldIn the mathematical disciplines of topology and geometry, an orbifold (for "orbit-manifold") is a generalization of a manifold. Roughly speaking, an orbifold is a topological space which is locally a finite group quotient of a Euclidean space. Definitions of orbifold have been given several times: by Ichirô Satake in the context of automorphic forms in the 1950s under the name V-manifold; by William Thurston in the context of the geometry of 3-manifolds in the 1970s when he coined the name orbifold, after a vote by his students; and by André Haefliger in the 1980s in the context of Mikhail Gromov's programme on CAT(k) spaces under the name orbihedron.
