We have designed and synthesized a new unsymmetrical zinc phthalocyanine based on 'push-pull' and extended pi-conjugation concept, PCH008. The new sensitizer was fully characterized by CHN anlysis, UV-Vis., fluorescence spectroscopies and cyclic voltammetry. The new sensitizer which upon anchoring onto nanocrystalline TiO2 film exhibit a short circuit current of 5.63 mA cm(-2), open circuit potential of 557.0 mV and a fill factor of 0.75 corresponding to an overall conversion efficiency of 2.35% under standard global air mass (AM) 1.5 solar conditions and compared its performance with literature reported phthalocyanine dyes.
Ulf Anders Hagfeldt, Thomas Moehl, Kazuteru Nonomura, Lorenzo Veronese
Ulf Anders Hagfeldt, Weiwei Zhang, Wenyan Li
Michael Graetzel, Jean-David Décoppet, Thomas Moehl