Synthesis of Functional Polyesters via Baylis-Hillman Polymerization
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Polypeptides derived from naturally occurring a-amino acids have emerged as a unique and versatile family of bio-inspired biomaterials that can be tailor-made for varying biomedical applications such as controlled drug release, gene delivery, tissue engine ...
The aim of this thesis has been to investigate the use of heat-activated shape memory polymers (SMPs) as novel smart actuators for the controlled delivery of fluids and their suitability for applications such as low-cost drug delivery. On heating to temper ...
With a span as long as the history of polymer science itself, post-polymerization modification represents a versatile platform for the preparation of diversely functionalized polymers from a single precursor. Starting with the initial efforts by Staudinger ...
The application of hydrogels as load-bearing biomedical components is often limited by their mechanical properties. Often an attempt to improve a hydrogel's stiffness is accompanied by a loss of toughness and swelling properties. In this work, we show that ...
Withstanding high pressures in polymeric microchannels is an important requirement for many biological applications. Here, a simple direct polymerization through a polyester photomask is applied to obtain monolithic polyethylene glycol (PEG)-modified poly( ...
Hydrogels are cross-linked, water-swollen polymer networks that are widely used as a biomaterial. The suitability of hydrogels as biomedical materials, especially as drug delivery systems depend on their bulk structure. The most important parameters used t ...
The ultimate control over chain self-assembly is key to unravel and optimize the relationship between film microstructure and charge carrier mobility in solution processable conjugated polymer semiconductors. Here we employ preparatory size exclusion chrom ...
Polyelectrolytes (PEL) and PEL complexes formed by electrostatic interaction are recognized as compounds with a remarkable potential for a wide field of applications. However, comprehensive knowledge about electrostatic and structural influences on the pol ...
Grid turbulence of polyethylene oxide (PEO) solutions (Polyox WSR-301 in H2O) has been investigated experimentally for three concentrations of 25, 50 and 100 weight ppm, at a turbulence Reynolds number based on a Taylor microscale of Re-lambda approximate ...
Trigger happy: Trigger-responsive chain-shattering polymeric therapeutics (CSPTs) were prepared by condensation polymerization of a UV- or hydrogen peroxide-responsive domain and a drug as co-monomers. Drug release can be started and stopped by starting an ...