Publication
Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid / Liquid Interfaces
Hubert Girault, Manuel Alejandro Méndez Agudelo, Bin Su, Raheleh Partovi Nia, Zdenek Samec
2010
Journal paper
2010
Journal paper
Abstract
Oxygen reduction catalyzed by cobalt(II) (2,3,7,8,12,13,17,18-octaethylporphyrin) [Co(OEP)] at soft interfaces is studied by voltammetry and biphasic reactions. When Co(OEP) is present in a solution of 1,2-dichloroethane in contact with an aqueous acidic solution, oxygen is reduced if the interface is positively polarized (water phase versus organic phase). This reduction reaction is facilitated when an additional electron donor, here ferrocene, is present in excess in the organic phase.
Official source
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