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This thesis reports on results of three different experiments of photo-induced structural dynamics in the condensed phase, investigated by time-resolved pump-probe spectroscopy with femtosecond time-resolution. In the first part, we address the ultrafast d ...
700nm parametric conversion in silica fiber from near-infrared to short-wave infrared band is reported for the first time. The conversion efficiency in excess of 40dB was measured between 1300nm signal and 2000nm idler band. ...
Carbon-13 labelled methane was injected into the outer divertor during a series of H-mode discharges on the last day of operations with the JET MkII-SRP divertor. Tiles from around the vessel were removed during the subsequent shutdown and surface deposits ...
The occurrence of an ultrathin SiO2 oxide layer at the interface between silicon and high-k dielectrics in metal-oxide-semiconductor devices contributes to degrading the capacitance of the gate stack. In this work, we investigate the dielectric and infrare ...
We report on a first-principles investigation of the structural and vibrational properties of vitreous germania (v-GeO2). Our work focuses on a periodic model structure of 168 atoms, but three smaller models are also studied for comparison. We first carry ...
The incorporation of carbon into the carbon monoxide and cyanide ligands of [NiFe]-hydrogenases has been investigated by using (13)C labelling in infrared studies of the Allochromatium vinosum enzyme and by (14)C labelling experiments with overproduced Hyp ...
We report quantitative dissociation yields for the reaction CH3OH (v(OH))-->nhnu CH3+OH induced by infrared multiphoton excitation of methanol pre-excited to various levels of the OH stretching vibration (v(OH)=0, 1, 3, 5). The yields are measured by detec ...
Glucose and lactate profiles in Chinese hamster ovary cell cultures were accurately monitored in real time and in situ during three bioreactor batch cultures lasting 11, 15, and 15 days performed within a 60-day period. Monitoring was accomplished using in ...
We determine the fraction f of B atoms belonging to boroxol rings in vitreous boron oxide through a first-principles analysis. After generating a model structure of vitreous B2O3 by first-principles molecular dynamics, we address a large set of properties, ...
The dynamics of the ferric CN complexes of the heme proteins Myoglobin and Hb I from the clam Lucina pectinata upon Soret band excitation is monitored using IR and broad band visible pump-probe spectroscopy. The transient response in the UV-vis spectral re ...