Isothermal microcalorimetryIsothermal microcalorimetry (IMC) is a laboratory method for real-time monitoring and dynamic analysis of chemical, physical and biological processes. Over a period of hours or days, IMC determines the onset, rate, extent and energetics of such processes for specimens in small ampoules (e.g. 3–20 ml) at a constant set temperature (c. 15 °C–150 °C). IMC accomplishes this dynamic analysis by measuring and recording vs. elapsed time the net rate of heat flow (μJ/s = μW) to or from the specimen ampoule, and the cumulative amount of heat (J) consumed or produced.
Entropy as an arrow of timeEntropy is one of the few quantities in the physical sciences that require a particular direction for time, sometimes called an arrow of time. As one goes "forward" in time, the second law of thermodynamics says, the entropy of an isolated system can increase, but not decrease. Thus, entropy measurement is a way of distinguishing the past from the future. In thermodynamic systems that are not isolated, local entropy can decrease over time, accompanied by a compensating entropy increase in the surroundings; examples include objects undergoing cooling, living systems, and the formation of typical crystals.
MigmatiteMigmatite is a composite rock found in medium and high-grade metamorphic environments, commonly within Precambrian cratonic blocks. It consists of two or more constituents often layered repetitively: one layer is an older metamorphic rock that was reconstituted subsequently by partial melting ("neosome"), while the alternate layer has a pegmatitic, aplitic, granitic or generally plutonic appearance ("paleosome"). Commonly, migmatites occur below deformed metamorphic rocks that represent the base of eroded mountain chains.
Sodium silicateSodium silicate is a generic name for chemical compounds with the formula Na2xSiyO2y+x or (Na2O)x·(SiO2)y, such as sodium metasilicate Na2SiO3, sodium orthosilicate Na4SiO4, and sodium pyrosilicate Na6Si2O7. The anions are often polymeric. These compounds are generally colorless transparent solids or white powders, and soluble in water in various amounts. Sodium silicate is also the technical and common name for a mixture of such compounds, chiefly the metasilicate, also called waterglass, water glass, or liquid glass.
Ice segregationIce segregation is the geological phenomenon produced by the formation of ice lenses, which induce erosion when moisture, diffused within soil or rock, accumulates in a localized zone. The ice initially accumulates within small collocated pores or pre-existing cracks, and, as long as the conditions remain favorable, continues to collect in the ice layer or ice lens, wedging the soil or rock apart. Ice lenses grow parallel to the surface and several centimeters to several decimeters (inches to feet) deep in the soil or rock.
Ice lensIce lenses are bodies of ice formed when moisture, diffused within soil or rock, accumulates in a localized zone. The ice initially accumulates within small collocated pores or pre-existing crack, and, as long as the conditions remain favorable, continues to collect in the ice layer or ice lens, wedging the soil or rock apart. Ice lenses grow parallel to the surface and several centimeters to several decimeters (inches to feet) deep in the soil or rock. Studies from 1990 have demonstrated that rock fracture by ice segregation (i.
Frost heavingFrost heaving (or a frost heave) is an upwards swelling of soil during freezing conditions caused by an increasing presence of ice as it grows towards the surface, upwards from the depth in the soil where freezing temperatures have penetrated into the soil (the freezing front or freezing boundary). Ice growth requires a water supply that delivers water to the freezing front via capillary action in certain soils. The weight of overlying soil restrains vertical growth of the ice and can promote the formation of lens-shaped areas of ice within the soil.
Partial meltingPartial melting is the phenomenon that occurs when a rock is subjected to temperatures high enough to cause certain minerals to melt, but not all of them. Partial melting is an important part of the formation of all igneous rocks and some metamorphic rocks (e.g., migmatites), as evidenced by a multitude of geochemical, geophysical and petrological studies. The parameters that influence partial melting include the composition of the source rock, the pressure and temperature of the environment, and the availability of water or other fluids.
