Isothermal microcalorimetryIsothermal microcalorimetry (IMC) is a laboratory method for real-time monitoring and dynamic analysis of chemical, physical and biological processes. Over a period of hours or days, IMC determines the onset, rate, extent and energetics of such processes for specimens in small ampoules (e.g. 3–20 ml) at a constant set temperature (c. 15 °C–150 °C). IMC accomplishes this dynamic analysis by measuring and recording vs. elapsed time the net rate of heat flow (μJ/s = μW) to or from the specimen ampoule, and the cumulative amount of heat (J) consumed or produced.
Entropy as an arrow of timeEntropy is one of the few quantities in the physical sciences that require a particular direction for time, sometimes called an arrow of time. As one goes "forward" in time, the second law of thermodynamics says, the entropy of an isolated system can increase, but not decrease. Thus, entropy measurement is a way of distinguishing the past from the future. In thermodynamic systems that are not isolated, local entropy can decrease over time, accompanied by a compensating entropy increase in the surroundings; examples include objects undergoing cooling, living systems, and the formation of typical crystals.
Migmatitevignette|Une migmatite correspondant à une métatexite. On observe deux rubanements. L'un de couleur sombre (mésosome), l'autre plus claire (leucosome) lui-même bordé d'un fin liseré (mélanosome). vignette|Pli ptygmatique dans une migmatite. vignette|Migmatite recoupée par des dykes de dolérite. Une migmatite (du grec : "migma", mélange), parfois appelée gneiss granitisé ou anatexite, est une roche métamorphique qui résulte majoritairement d'une anatexie. On la trouve dans des zones de gradient métamorphique moyen à élevé.
Sodium silicateSodium silicate is a generic name for chemical compounds with the formula Na2xSiyO2y+x or (Na2O)x·(SiO2)y, such as sodium metasilicate Na2SiO3, sodium orthosilicate Na4SiO4, and sodium pyrosilicate Na6Si2O7. The anions are often polymeric. These compounds are generally colorless transparent solids or white powders, and soluble in water in various amounts. Sodium silicate is also the technical and common name for a mixture of such compounds, chiefly the metasilicate, also called waterglass, water glass, or liquid glass.
Ice segregationIce segregation is the geological phenomenon produced by the formation of ice lenses, which induce erosion when moisture, diffused within soil or rock, accumulates in a localized zone. The ice initially accumulates within small collocated pores or pre-existing cracks, and, as long as the conditions remain favorable, continues to collect in the ice layer or ice lens, wedging the soil or rock apart. Ice lenses grow parallel to the surface and several centimeters to several decimeters (inches to feet) deep in the soil or rock.
Ice lensIce lenses are bodies of ice formed when moisture, diffused within soil or rock, accumulates in a localized zone. The ice initially accumulates within small collocated pores or pre-existing crack, and, as long as the conditions remain favorable, continues to collect in the ice layer or ice lens, wedging the soil or rock apart. Ice lenses grow parallel to the surface and several centimeters to several decimeters (inches to feet) deep in the soil or rock. Studies from 1990 have demonstrated that rock fracture by ice segregation (i.
Frost heavingFrost heaving (or a frost heave) is an upwards swelling of soil during freezing conditions caused by an increasing presence of ice as it grows towards the surface, upwards from the depth in the soil where freezing temperatures have penetrated into the soil (the freezing front or freezing boundary). Ice growth requires a water supply that delivers water to the freezing front via capillary action in certain soils. The weight of overlying soil restrains vertical growth of the ice and can promote the formation of lens-shaped areas of ice within the soil.
Fusion partiellevignette| 300px| Les laves proviennent de la différenciation chimique de magmas formés par fusion partielle. La fusion partielle d'une roche correspond à la fusion d'une partie de ses minéraux, généralement dans des proportions différentes de celles de la roche elle-même. La température de la roche est telle que le solidus de la roche est dépassé, alors que son liquidus n'est pas atteint. Lorsque la roche source est ainsi en partie fondue, on a la formation d'un liquide magmatique entre les cristaux non encore fondus : les phases solides et liquide coexistent.
