Publication

Solution viscosity and flocculation characteristics of linear polymeric flocculants in various media

Abstract

Rheological characteristics of linear copolymers of acrylamide (AM) and acryloyloxyethyltrimethyl ammonium chloride (Q9), differing in molar mass and chemical composition, have been studied in distilled water (DW) and industrial water (IW) obtained from a paper mill. For all copolymers, the shear viscosity, mu, was much lower as the ionic strength of the water increased, with near Newtonian behaviour observed at high ionic strengths. In DW, the polymer solutions were yield pseudoplastic. Comparison of the behaviour of all flocculants at the same shear rate in the two media was accomplished by modelling the rheological data.

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Related concepts (34)
Rheology
Rheology (riːˈɒlədʒi; ) is the study of the flow of matter, primarily in a fluid (liquid or gas) state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is a branch of physics, and it is the science that deals with the deformation and flow of materials, both solids and liquids. The term rheology was coined by Eugene C. Bingham, a professor at Lafayette College, in 1920, from a suggestion by a colleague, Markus Reiner.
Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity is defined scientifically as a force multiplied by a time divided by an area. Thus its SI units are newton-seconds per square metre, or pascal-seconds. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion.
Copolymer
In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are sometimes called bipolymers. Those obtained from three and four monomers are called terpolymers and quaterpolymers, respectively. Copolymers can be characterized by a variety of techniques such as NMR spectroscopy and size-exclusion chromatography to determine the molecular size, weight, properties, and composition of the material.
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