Rotational spectroscopyRotational spectroscopy is concerned with the measurement of the energies of transitions between quantized rotational states of molecules in the gas phase. The spectra of polar molecules can be measured in absorption or emission by microwave spectroscopy or by far infrared spectroscopy. The rotational spectra of non-polar molecules cannot be observed by those methods, but can be observed and measured by Raman spectroscopy.
Emission spectrumThe emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to an electron making a transition from a high energy state to a lower energy state. The photon energy of the emitted photon is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum.
X-ray photoelectron spectroscopyX-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique based on the photoelectric effect that can identify the elements that exist within a material (elemental composition) or are covering its surface, as well as their chemical state, and the overall electronic structure and density of the electronic states in the material. XPS is a powerful measurement technique because it not only shows what elements are present, but also what other elements they are bonded to.
Atomic clockAn atomic clock is a clock that measures time by monitoring the resonant frequency of atoms. It is based on atoms having different energy levels. Electron states in an atom are associated with different energy levels, and in transitions between such states they interact with a very specific frequency of electromagnetic radiation. This phenomenon serves as the basis for the International System of Units' (SI) definition of a second:The second, symbol s, is the SI unit of time.
Diffuse seriesThe diffuse series is a series of spectral lines in the atomic emission spectrum caused when electrons jump between the lowest p orbital and d orbitals of an atom. The total orbital angular momentum changes between 1 and 2. The spectral lines include some in the visible light, and may extend into ultraviolet or near infrared. The lines get closer and closer together as the frequency increases never exceeding the series limit. The diffuse series was important in the development of the understanding of electron shells and subshells in atoms.
Normal spaceIn topology and related branches of mathematics, a normal space is a topological space X that satisfies Axiom T4: every two disjoint closed sets of X have disjoint open neighborhoods. A normal Hausdorff space is also called a T4 space. These conditions are examples of separation axioms and their further strengthenings define completely normal Hausdorff spaces, or T5 spaces, and perfectly normal Hausdorff spaces, or T6 spaces. A topological space X is a normal space if, given any disjoint closed sets E and F, there are neighbourhoods U of E and V of F that are also disjoint.
Sierpiński spaceIn mathematics, the Sierpiński space (or the connected two-point set) is a finite topological space with two points, only one of which is closed. It is the smallest example of a topological space which is neither trivial nor discrete. It is named after Wacław Sierpiński. The Sierpiński space has important relations to the theory of computation and semantics, because it is the classifying space for open sets in the Scott topology.
Principal series (spectroscopy)In atomic emission spectroscopy, the principal series is a series of spectral lines caused when electrons move between p orbitals of an atom and the lowest available s orbital. These lines are usually found in the visible and ultraviolet portions of the electromagnetic spectrum. The principal series has given the letter p to the p atomic orbital and subshell. The lines are absorption lines when the electron gains energy from an s subshell to a p subshell. When electrons descend in energy they produce an emission spectrum.
Uniform spaceIn the mathematical field of topology, a uniform space is a topological space with additional structure that is used to define uniform properties, such as completeness, uniform continuity and uniform convergence. Uniform spaces generalize metric spaces and topological groups, but the concept is designed to formulate the weakest axioms needed for most proofs in analysis. In addition to the usual properties of a topological structure, in a uniform space one formalizes the notions of relative closeness and closeness of points.
Spontaneous parametric down-conversionSpontaneous parametric down-conversion (also known as SPDC, parametric fluorescence or parametric scattering) is a nonlinear instant optical process that converts one photon of higher energy (namely, a pump photon), into a pair of photons (namely, a signal photon, and an idler photon) of lower energy, in accordance with the law of conservation of energy and law of conservation of momentum. It is an important process in quantum optics, for the generation of entangled photon pairs, and of single photons.
