Subwavelength Metallic Structures for Sensing

Following rapid developments in biotechnology and medicine, optical sensing promises to be extremely important in various applications such as drug discovery, environmental monitoring, etc. Refractive index (RI) based optical sensing is straightforward to monitor or analyze the physical and chemical properties of substances. Among diverse configurations developed for RI detection, plasmonics devices using nanoscale patterned metals are particularly promising. Nano-structured metallic devices enable field confinement in a volume smaller than the diffraction limit. Moreover, they present possibilities for device miniaturization and sensor multiplexing on the same substrate. This thesis is dedicated to investigating a sensing platform combining nanostructured metallic cavities and dielectric waveguides. Periodically structured Au films have been explored for their application in local RI sensing. Two structures are considered: the slot waveguide cavity (SWC) and the annular aperture array (AAA). The SWC is composed of a Au film structured by a periodic slot array, which is deposited on a silicon (Si) waveguide. The evanescent field overlap correlates the resonant optical response of the cavity to the transmission spectrum of the Si waveguide. Theoretical studies, fabrication and characterization have been performed to verify the RI sensing ability for extremely subwavelength slot dimensions (30 nm slot width for 20 nm-thick Au film and 700 nm cavity length). The experimental sensitivity, 730 ± 10 nm/RIU, corresponds to the theory and an optimum resolution of 5.8 × 10-5 RIU is anticipated for RI detection. For the AAA device, the patterned Au film is directly embedded in a Si3N4 waveguide. The Fabry-Pérot-like resonance of the Au cavity results in a resonant reflection, enabling a device sensitive to RI variations. For a wide range of analytes, the theoretical sensitivity is 764 nm/RIU in the near-infrared wavelength range. Compared with other resonance based photonic sensors, the two devices exhibit comparable sensitivities to the RI variation. The small metallic cavity implies a local detection on nano scale and the sample volume can be on the order of a femtolitre. Furthermore, the planar configuration permits easy integration with other photonic devices. Parallel sensing using compatible sensors on the same substrate is anticipated for the realization of portable and low-cost sensor systems.

Enhanced spontaneous emission from quantum dots in short photonic crystal waveguides

Laurent Balet

We report a study of the quantum dot (QD) emission in short photonic crystal waveguides. We observe that the quantum dot photoluminescence intensity and decay rate are strongly enhanced when the emission energy is in resonance with Fabry-Perot (FP) cavity modes in the slow-light regime of the dispersion curve. The experimental results are in agreement with previous theoretical predictions and are further supported by three-dimensional finite element simulations. Our results show that the combination of slow group velocity and Fabry-Perot cavity resonance provide an avenue to efficiently channel photons from quantum dots into waveguides for integrated quantum photonic applications. (C) 2012 American Institute of Physics. [doi:10.1063/1.3683541]

2012

Near-field imaging

Libo Yu

Bloch surface waves (BSWs) are surface electromagnetic waves excited at the interface between a truncated periodic dielectric multilayer and a surrounding medium. This particular solution to the Maxwell equations in stratified media has been known since the late 1970s. However, few studies have been conducted till now on the manipulation and control of BSW propagation over 2D surfaces of photonic structures. There are several advantages provided by BSW propagation on almost flat surfaces. Due to the use of dielectric materials, losses are very low, thus allowing the propagation of BSWs over long distances. Another advantage in using BSWs is the possibility of operating within a broad range of wavelengths by properly designing a suitable multilayered structure. Furthermore, since the maximum intensity associated with BSWs can be tuned on the surface, a strong field intensity increased by several orders of magnitude can be achieved and can thereby enhance the field close to the structure's surface. This tunable localized field confinement is particularly attractive in fluorescence biosensing. In the following, we will use an exemplary BSW-sustaining multilayer as a general platform suitable for manipulating and controlling BSW propagation on its surface in the spectral range of telecom wavelengths. Several 2D optical photonic devices can be implemented starting from an ultra-thin (~ λ /15) polymer layer spun on the multilayer, which can be subsequently shaped as desired. The presence of the polymer modifies the local effective refractive index, enabling a direct manipulation of the BSWs. We experimentally and theoretically demonstrate that BSWs can be diffracted, focused, coupled and made resonating by locally shaping the geometries of 2D photonic devices—such as lenses, prisms, gratings, bended waveguides and waveguide couplers—on the multilayer. One of the main advantages is that these 2D photonic devices can have arbitrary shapes, which are difficult to obtain in 3D. The strong point of the platform concept is that a thin-film multilayer enables standard-wafer-scale production. The top surface can be modified to customize a 2D micro-system by, e.g., e-beam writing, optical lithography, stamping or other replication techniques. Since a BSW can be considered as a 2D wave and it is bounded at the surface of the multilayer, near-field imaging is one of the preferred tools to directly monitor and characterize the near field produced on the structured multilayered surface mentioned above. A multi-heterodyne scanning near-field optical microscope (MH-SNOM) developed in our lab (EPFL-OPT) makes near-field characterization possible. The operation wavelength is in the near infrared range (1460 nm–1580 nm). A polarization-retrieval method is developed in this thesis to measure and characterize the near-field polarization response for arbitrary polarization- sensitive photonic nano-devices, such as photonic crystal microcavities, waveguides, thin films, nanoparticles, spiral gratings and other near-field polarization-sensitive imaging applications. Polarization retrieval is easily accessible in far-field microscopy, but is challenging for the near field. This is because when a SNOM probe interacts with the near field and scatters the signal to the far field, the near-field polarization may be considerably altered. In this thesis, the developed method uses an isotropic region in the vicinity of the nanostructure as a calibration area, whose known polarization properties provide a global criterion to calibrate and quantify the polarization distortion induced by the detection system. It is then applied on the field measured above the structure of interest to compensate and reconstruct its complex field response. We experimentally show the effectiveness of the method on a silicon form- birefringent grating (FBG) with significant polarization diversity. Three spatial dimensional near-field measurements are in agreement with theoretical predictions obtained with rigorous coupled-wave analysis (RCWA). Pseudo-far- field (~10λ away from the surface) measurements are performed to obtain the effective refractive index of the FBG, emphasizing the validity of the proposed method. This reconstruction algorithm makes the MH-SNOM a powerful tool to analyze concurrently the polarization-dependent near-field optical response of any nanostructures with subwavelength resolution as long as a calibration area is available in close proximity.

EPFL2013

Tunable and Broadband Nanostructured Photonic Devices

Pierre-Yves Baroni

The main topic of this thesis is the fabrication and characterization of structures smaller than the wavelength of light, for operation in the visible or near infrared spectral range. In the first part of this thesis, the fabrication of periodic structures in one and two dimensions with an interference photolithography technique is described in detail. The structure periodicities that have been fabricated with this process ranges between 270 nm and a few microns on areas that can be as large as 100 cm2. Typical structure thicknesses are approximately equal to the period. In particular, a square lattice of pillars with a period of 270 nm has been created on the (non-flat) surface of a quartz microlens array and exhibits anti-reflective properties. Experimental results show a 15 % attenuation of the reflectivity and a 3 % enhancement of the transmissivity over the visible spectral range. In the second part of the thesis the structures are fabricated by e-beam lithography to ensure very precise devices shapes. The experimental results are obtained in the infrared range with two different structures, called photonic crystals. The first structure, a superprism, is a triangular lattice of pillars infiltrated by liquid crystals. A displacement of the output light spot is measured to be 20.5 µm for a wavelength variation of 27 nm. The structure length is 70 µm. The device, based on standard silicon technology, should allow integration of the device as a multiplexer/demultiplexer system into optical micro-circuits. The second structure, a tunable resonant cavity, is a wavelength filter working in the near infrared spectrum. The active area is composed of a photonic waveguide with a triangular lattice made of sub-micrometer holes. Additional nanostructuring in the light waveguide acts as a resonant cavity. The tunability of the device is obtained due to the liquid crystals which are infiltrated into the nanostructure. A 32 nm shift of the transmitted light peak inside the photonic band gap is measured by changing the temperature from room temperature to 45 °C.