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Bright Blue Phosphorescence from Cationic Bis-Cyclometalated Iridium(III) Isocyanide Complexes

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Ultrafast Excited-State Dynamics ef [Re(L)(CO)(3)(bpy)](n) Complexes: Involvement of the Solvent

Majed Chergui, Frank van Mourik, Andrea Cannizzo, Amal El Nahhas

Ultrafast excited-state dynamics of Re(L)(CO)(3)(bpy) (L = Cl, Br, n = 0; L = 4-ethyl-pyridine (Etpy), n = 1+; bpy = 2,2'-bipyridine) have been investigated in dimethylformamide (DMF) solution by fluorescence up-conversion (FIUC) and UV - vis transien ...

American Chemical Society2010

N-Aryl Chromophore Ligands for Bright Europium Luminescence

Rosario Scopelliti, Jean-Claude Bünzli, Svetlana Eliseeva

Sterically hindered N-aryl-benzimidazole pyridine-2-carboxylic acids (aryl = phenyl, 4-biphenyl, 2-naphthyl) readily form homoleptic, neutral, nine-coordinate europium complexes which display efficient sensitized luminescence in solid state and in dichloro ...

American Chemical Society2010

White-light phosphorescence emission from a single molecule: application to OLED

Michael Graetzel, Mohammad Khaja Nazeeruddin, Kuppuswamy Kalyanasundaram, Filippo de Angelis

A simple mononuclear cyclometallated iridium(III) complex exhibits white photo- and electro-luminescence in the wavelength range from 440 to 800 nm, which originates from a single emitting excited state of mixed character. ...

2009

A facile strategy for preparation of fluorescent SWNT complexes with high quantum yields based on ion exchange

Paul Joseph Dyson, Zhaofu Fei

The fluorescent imidazolium salt (1,3-bis(9-anthracenylmethyl)imidazolium chloride, [bamim]Cl) has been grafted onto the surfaces of single-walled carbon nanotubes (SWNTs) using an ion exchange strategy based on metathesis of the K+ ion in CO2K derivatized ...

2008

Dimeric Complexes of Lanthanide(III) Hexafluoroacetylacetonates with 4-Cyanopyridine N-Oxide: Syn thesis, Crystal Structure, Magnetic and Photoluminescent Properties

Jean-Claude Bünzli, Frédéric Gumy, Svetlana Eliseeva

A series of new mixed-ligand lanthanide complexes [Ln(hfa)3(4-cpyNO)]2 (Ln = SmIII-HoIII and TmIII; hfa- = hexafluoroacetylacetonate; 4-cpyNO = 4-cyanopyridine N-oxide) have been synthesised by treating the corresponding lanthanide hexafluoroacetylacetonat ...

2006

Space charge and polarization effects upon doping organic light-emitting diodes with pyran-containing donor-acceptor molecules

Frank Nüesch, Libero Zuppiroli, Yiming Cao, Detlef Berner, Xiao Wang

Doping of organic light-emitting devices using highly luminescent molecules is a well-established strategy to improve brightness, efficiency and lifetime or to adjust emission color and color purity. Laser dyes from the pyran-containing donor-acceptor fami ...

VSP BV, Zeist, Netherlands2004

Manganese doped ZnS nanoparticles

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Nanostructured materials can be defined as those materials whose structural elements - clusters, crystallites or molecules - have dimensions in the 1-100 nm range. The explosion in both academic and industrial interest over the past 20 years arises from th ...

EPFL2004

Optical properties of In(Ga)As/GaAs quantum dot-based devices emitting at 1.3[mu]m

Self-assembled quantum-dots (QDs) represent a distributed ensemble of zero dimensional structures with a near-singular density of states. Implemented as the active medium in a diode laser their unique properties lead to improved and often novel characteris ...

EPFL2004

Spectral and kinetic fluorescence properties of native and nonisomerizing retinal in bacteriorhodopsin

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Steady-state and picosecond (ps) fluorescence studies of wild-type bacteriorhodopsin (wt-bR) and of a nonisomerizing analog locked in the all-trans configuration have been performed. Extending earlier work done by femtosecond absorption spectroscopy, we ob ...

2001

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