Publications related to Hydrogen bonding control of self-assembly: Simple isophthalic acid derivatives form cyclic hexameric aggregates

Dicarboxylate-Bridged Ruthenium Complexes as Building Blocks for Molecular Nanostructures

Rosario Scopelliti, Kay Severin, Benan Kilbas

Ruthenium complexes with bridging dicarboxylate ligands were combined with 1,2-di-4-pyridylethylene (dpe), 2,4,6-tri-4-pyridyltriazine (4-tpt), or 2,4,6-tri-3-pyridyltriazine (3-tpt) to give a tetranuclear rectangle or hexanuclear coordination cages. The c ...

2012

Chemistry of Nitrosyliron Complexes Supported by a beta-Diketiminate Ligand

Florent Emmanuel Héroguel

Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6- diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO) 2(Ar-nacnac)] (2) ...

American Chemical Society2011

Connection of Metallamacrocycles via Dynamic Covalent Chemistry: A Versatile Method for the Synthesis of Molecular Cages

Rosario Scopelliti, Kay Severin, Clément Schouwey, Anton Granzhan

A modular approach for the synthesis of cage structures is described. Reactions of [(arene)RuCl2]2 [arene = p-cymene, 1,3,5-C6H3Me3, 1,3,5-C6H3(i-Pr)3] with formyl-substituted 3-hydroxy-2-pyridone ligands provide trinuclear metallamacrocycles with pendant ...

2011

Reaction of C60 with Hydrogen Gas: In Situ Monitoring and Pathways

Yury Tsybin

Kinetics and pathways of C60 reaction with hydrogen gas were studied in a broad temperature interval and over extended periods of time. Specifically, hydrogenation was monitored in situ at high temperature and high hydrogen pressure conditions using the gr ...

American Chemical Society2011

Computational study of drug binding to the membrane-bound tetrameric M2 peptide bundle from influenza A virus

Matteo Dal Peraro

The M2 protein of influenza A virus performs the crucial function of transporting protons to the interior of virions enclosed in the endosome. Adamantane drugs, amantadine (AMN) and rimantidine (RMN), block the proton conduction in some strains, and have b ...

2011

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

Hubert Girault, Manuel Alejandro Méndez Agudelo, Bin Su, Peiyu Ge, Imren Hatay, Zdenek Samec

Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH+, as an active intermediate species, producing hydrogen perox ...

Royal Society of Chemistry2010

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

Paul Joseph Dyson, Gabor Laurenczy, Andrew Douglas Phillips

The water-soluble iridium(III) complexes [CpIr(PTA)Cl2] (1) and [CpIr(PTA)2Cl]Cl (2) (PTA = 1,3,5-triaza-7-phosphaadamantane) have been synthesised and characterised by spectroscopy and X-ray crystallography. The complexes were evaluated as catalyst prec ...

2008

Homogeneous catalytic decomposition of formic acid for high pressure hydrogen generation

Céline Fellay

The main obstacles in the widespread use of hydrogen as energetic alternative to fossil fuels are storage problems intrinsically linked to its extremely light and explosive nature. Since no ideal storage systems currently exist, reversible fixation of hydr ...

EPFL2008

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Albert Renken, Lioubov Kiwi, Martin Grasemann

Systematic studies of mass transfer interactions with intrinsic reaction kinetics were performed for the threephase selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE) over a modified Pd/CaC

{O}_{3}

catalyst under solvent ...

2008

Hydrogenation of C60 at 2GPa pressure and high temperature

Yury Tsybin

Hydrogenation of C60 at 2 GPa and 723-823 K was performed with thermal decompn. of LiAlH4 as a hydrogen source. Anal. of hydrogenation products showed that the method can produce not only C60H36, but also hydrofullerides C60Hx with 44 < x < 52. Unlike othe ...

2006

Hydrogen bonding control of self-assembly: Simple isophthalic acid derivatives form cyclic hexameric aggregates

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Dicarboxylate-Bridged Ruthenium Complexes as Building Blocks for Molecular Nanostructures

Chemistry of Nitrosyliron Complexes Supported by a beta-Diketiminate Ligand

Connection of Metallamacrocycles via Dynamic Covalent Chemistry: A Versatile Method for the Synthesis of Molecular Cages

Reaction of C60 with Hydrogen Gas: In Situ Monitoring and Pathways

Computational study of drug binding to the membrane-bound tetrameric M2 peptide bundle from influenza A virus

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

Homogeneous catalytic decomposition of formic acid for high pressure hydrogen generation

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring

Hydrogenation of C60 at 2GPa pressure and high temperature

Hydrogenation of C60 at 2GPa pressure and high temperature

Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media

Reaction of C60 with Hydrogen Gas: In Situ Monitoring and Pathways

Connection of Metallamacrocycles via Dynamic Covalent Chemistry: A Versatile Method for the Synthesis of Molecular Cages

(Pentamethylcyclopentadienyl)iridium-PTA (PTA = 1,3,5-Triaza-7-phosphaadamantane) Complexes and Their Application in Catalytic Water Phase Carbon Dioxide Hydrogenation

Dicarboxylate-Bridged Ruthenium Complexes as Building Blocks for Molecular Nanostructures

Computational study of drug binding to the membrane-bound tetrameric M2 peptide bundle from influenza A virus

Chemistry of Nitrosyliron Complexes Supported by a beta-Diketiminate Ligand

Homogeneous catalytic decomposition of formic acid for high pressure hydrogen generation

Three-Phase Catalytic Hydrogenation of a Functionalized Alkyne: Mass Transfer and Kinetic Studies with in Situ Hydrogen Monitoring