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Measured binding coefficients for iodine and ruthenium dyes; implications for recombination in dye sensitised solar cells

Related publications (42)

One-pot synthesis of functionalized bis(trifluoromethylated)benziodoxoles from iodine(i) precursors

Jérôme Waser, Xingyu Liu, Nieves Pilar Ramirez Hernandez, Tobias Michael Milzarek

Bis(trifluoromethylated)benziodoxoles (Bx) are broadly used cyclic hypervalent iodine reagents due to their stability and unique chemical properties. However, current methods to access them require several steps and long reaction times, making their synthe ...
2023

Lateral Intermolecular Electronic Interactions of Diketopyrrolopyrrole D−π–A Solar Dye Sensitizers Adsorbed on Mesoporous Alumina

Jacques-Edouard Moser, Ulf Anders Hagfeldt, Heewon Bahng

The development of push−pull organic dyes utilizing the donor−(π-conjugated bridge)−acceptor (D−π−A) motif has induced a paradigm shift in the design of efficient nanocrystalline dye-sensitized solar cells (DSSCs), offering control over the aesthetic prope ...
2018

Experimental demonstration of the water-holding property of three-dimensional vortices

When injecting dye into a vertical vortex generated by a commercial magnetic stirrer, one finds that dye remains captured around the vortex core over minutes, while it gets mixed with the water outside this region rather rapidly. Thus, considering its hori ...
2018

Significance of pi-bridge contribution in pyrido[3,4-b]pyrazine featured D-A-pi-A organic dyes for dye-sensitized solar cells

Shaik Mohammed Zakeeruddin, Fabrizio Giordano, Zhongjin Shen, Yelin Hu, Xiaoyu Zhang

The 3,4-ethylenedioxythiophene (EDOT) pi-bridge is one of the most commonly used building blocks for sensitizers in dye-sensitized solar cells (DSSCs). We investigated its influence on the molecular structure, the photophysical and electrochemical properti ...
Chinese Chemical Soc2017

The Nature of Ion Conduction in Methylammonium Lead Iodide: A Multimethod Approach

Michael Graetzel, Joachim Maier, Alessandro Senocrate

By applying a multitude of experimental techniques including H-1, N-14, Pb-207 NMR and I-127 NMR/NQR, tracer diffusion, reaction cell and doping experiments, as well as stoichiometric variation, conductivity, and polarization experiments, iodine ions are u ...
Wiley-Blackwell2017

Unraveling the Dual Character of Sulfur Atoms on Sensitizers in Dye-Sensitized Solar Cells

Mohammad Khaja Nazeeruddin, Jacques-Edouard Moser, Peng Gao, Thomas Moehl, Joël Teuscher, Aswani Yella, Sadig Aghazada

Cyclometalated ruthenium sensitizers have been synthesized that differ with number of thiophene units on the auxiliary ligands. Sensitizers possessing four (SA25, SA246, and SA285) or none (SA282) sulfur atoms in their structures, were tested in solar cell ...
Amer Chemical Soc2016

Novel Blue Organic Dye for Dye-Sensitized Solar Cells Achieving High Efficiency in Cobalt-Based Electrolytes and by Co-Sensitization

Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Jiahuan Zhang, Kazuteru Nonomura, Yan Hao, Yasemin Saygili, Anna Eriksson, Enrico Polanski

Blue and green dyes as well as NIR-absorbing dyes have attracted great interest because of their excellent ability of absorbing the incident photons in the red and near-infrared range region. A novel blue D-pi-A dye (Dyenamo Blue), based on the diketopyrro ...
2016

A study of oligothiophene-acceptor dyes in p-type dye-sensitized solar cells

Lei Zhang, Ulf Anders Hagfeldt, Peng Liu

Two new dyes, E1 and E2, equipped with triphenylamine as the electron donor, oligothiophene as the linker and different electron acceptor groups, have been designed and synthesized as photosensitizers for p-type dye-sensitized solar cells (p-DSCs). A syste ...
Royal Soc Chemistry2016

Rationalizing Fluorescence Quenching in meso-BODIPY Dyes

Alberto Fabrizio, Antonio Prlj

meso-Substituted boron-dipyrromethene (BODIPY) dyes are a puzzling class of molecules, which feature contrasting emissive behaviors. The full mechanistic picture for these distinctive properties is still missing. Using static and dynamic excited state comp ...
Royal Soc Chemistry2016

Preparation of cationic azo compounds

Kay Severin, Alexander Tskhovrebov

The present invention relates to a novel method for preparing cationic azo compounds, which preferably can be used as dyes. Further, the invention relates to novel cationic azo compounds and the use of N2O in the synthesis of azo-imidazolium dyes. ...
2016

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