Determination of the molecular structure of the short-lived light-induced high-spin state in the spin-crossover compound [Fe(6-mepy)(3)tren](PF6)(2)
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Long-range magnetic ordering and short-range spin correlations in layered noncentrosymmetric orthogermanate Li2MnGeO4 were studied by means of polarized and unpolarized neutron scattering. The combined Rietveld refinement of synchrotron and neutron powder ...
3d transition-metal oxide materials with strong electron correlations and low dimensionality give rise to emerging exotic phases. Resonant inelastic X-ray scattering (RIXS) has developed as a powerful spectroscopic tool for probing the collective excitatio ...
By means of Mn-Cu transmetalation, we incorporated Mn atoms in an array of TCNQ (7,7,8,8-tetracyanoquinodimethane) grown on Cu(100), forming a long range ordered and commensurate metal-organic coordination network (MOCN). Preliminary Sn alloying of the Cu( ...
The vast chemical space of metal and ligand combinations in Transition Metal Complexes (TMCs) gives rise to a rich variety of electronic excited states with local and non-local character such as intra-ligand (IL), metal-centered (MC), metal-to-ligand (MLCT ...
The time-window for processing electron spin information (spintronics) in solid-state quantum electronic devices is determined by the spin-lattice and spin-spin relaxation times of electrons. Minimizing the effects of spin-orbit coupling and the local magn ...
We report a novel crossover behavior in the long-range-ordered phase of a prototypical spin-1/2 Heisenberg antiferromagnetic ladder compound (C7H10N)(2)CuBr4. The staggered order was previously evidenced from a continuous and symmetric splitting of (NNMR)- ...
The growing library of two-dimensional layered materials is providing researchers with a wealth of opportunity to explore and tune physical phenomena at the nanoscale. Here, we review the experimental and theoretical state-of-art concerning the electron sp ...
The spin relaxation time in solids is determined by several competing energy scales and processes, and distinct methods are called for to analyze the various regimes. We present a stochastic model for the spin dynamics in solids which is equivalent to solv ...
The thermal spin crossover (SCO) phenomenon refers to an entropy-driven spin transition in some materials based on d(6)-d(9) transition metal complexes. While its molecular origin is well known, intricate SCO behaviours are increasingly common, in which th ...
Valence and spin states of Fe were investigated in a glass of almandine (Fe3Al2Si3O12) composition to 91 GPa by X-ray emission spectroscopy and energy- and time-domain synchrotron Mossbauer spectroscopy in the diamond-anvil cell. Changes in optical propert ...