Functional polypeptide and hybrid materials: Precision synthesis via alpha-amino acid N-carboxyanhydride polymerization and emerging biomedical applications
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A series of bis(trifluoromethylsulfonyl)amide based "polymeric ionic liquids" (PILs) as high molecular mass analogues of the corresponding imidazolium, ammonium and pyrrolidinium ionic liquids (ILs) was synthesized with high purity and fully characterized ...
Herein the concept of tandem postpolymerization modification as a versatile route to synthesize well-defined, highly functionalized polymers is introduced. Poly(pentafluorophenyl methacrylate) obtained by atom transfer radical polymerization was first modi ...
Proteins have been modified with polymers in diverse manners over the past 30 years. However, while proteins have been used to prepare many functional constructs, they are sensitive biomolecules and their bioactivity can be either positively or negatively ...
In this work we explored the possibility of obtaining nanocrystalline (Y0.5Lu0.5)2O3 powders, doped with europium and co-doped with praseodium, employing polymer complex solution synthesis. Polyethylene glycol, with average molecular weight 200, served bot ...
The achievement of high ionic conductivity in single-ion conducting polymer electrolytes is one of the important aims for various electrochemical devices including modern lithium batteries. One way to enhance the ionic conductivity in polyelectrolyte syste ...
This article discusses the synthesis and properties of dendritic and hyperbranched polyamides. The first part of the article focuses on peptide dendrimers and starts with providing an overview of the synthetic pathways that have been used to prepare dendri ...
This contribution explores different strategies for the synthesis of side chain functional polydepsipeptides. First, the ring-opening polymerization of side chain functional morpholine-2,5-diones is revisited and the optimized reaction conditions used for ...
Bis-1,3(N,N,N-trimethylammonium)-2-propylmethacrylate dichloride (di-M) and bis-1,3(N,N,N-trimethylammonium)-2-propylacrylate dichloride (di-A), two new double-charged monomers, were the subject of the research reported in this thesis. These monomers provi ...
The preparation of synthetic polymers with exact control over chain length and monomer sequence is one of the long-standing challenges in polymer science. Nature perfectly masters the synthesis of high molecular weight, perfectly monodisperse polypeptides ...
Bioactive hydrogels formed by Michael-type addition reactions of end-functionalized poly(ethylene glycol) macromers with cysteine-containing peptides have been described as extracellular matrix mimetics and tissue engineering scaffolds. Although these mate ...