Electrochemical assessment of water|ionic liquid biphasic systems towards cesium extraction from nuclear waste
Graph Chatbot
Chat with Graph Search
Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.
DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.
Non-destructive and destructive methods have been compared to validate their corresponding assessed accuracies in the measurement of 134Cs/137Cs and 154Eu/137Cs isotopic concentration ratios in four spent UO2 fuel samples with very high (52 and 71 GWd/t) a ...
Metal ions are essential elements in all living systems. Their detections and identifications in biological processes require different methodologies. Mass spectrometry is one of the commonly used techniques in bioinorganic analyses to fulfill these requir ...
In the inert matrix fuel concept, plutonium reprocessed from spent fuel is burned in an inert matrix, e.g. yttria-stabilized zirconia. Coming from wet reprocessing, the internal gelation can perform an easy micro-spheres production. Utilization of these pa ...
The improvement of the "radiological cleanliness" of nuclear energy is a primary goal in the development of advanced reactors and fuel cycles. The multiple recycling of actinides in advanced nuclear systems with fast neutron spectra represents a key option ...
Solutions of the strong complexing agent ethylenediaminetetraacetic acid (EDTA) and Cu, Pb, Cd, Al, and Fe(III) were examined by electrospray mass spectrometry (ES/MS). Uncomplexed EDTA and metal-EDTA complexes survive the electrospray process intact and c ...
A new polydentate tripodal ligand T2soxMe was synthesized to take advantage of the chelating effect of tridentate 8- hydroxyquinolinate subunits. Potentiometric and spectrophotometric titrations reveal seven pKa values of between 3.7 and 10.2. In water, th ...
A new macrocyclic ligand, L3, has been synthesised, based on the cyclen framework grafted with three phenacyl light-harvesting groups and a C5-alkyl chain bearing a carboxylic acid function as a potential linker for biological material. Acidity constant ...
The dissolution and transformation of soddyite ([UO2]2SiO4·2H2O) have been examined in aqueous suspension at pH 6 and 0.01 M NaNO3. Soddyite is an important component of the paragenetic sequence of secondary minerals that arises from the weathering of uran ...
One of the principal research axes related to nuclear energy concerns the management of nuclear wastes. In this context, certain innovative pathways are being explored to provide options which could lead to a major reduction of the quantities of radioactiv ...
1H, 19F-HOESY studies on the ionic liq. based on 1-butyl-3-methylimidazolium tetrafluoroborate, [C4C1i.m.]BF4, [C4C1i.m.][N(OTf)2], and, partially, [C4C1i.m.]PF6, are reported. The addn. of methanol separates the ions; however, in dichloromethane soln. the ...
