Identification of Tyrosine-Phosphorylated Peptides Using Cold Ion Spectroscopy
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We report on microscopic observation of solvation by argon atoms of excited states of an ethylenic-like mol., TDMAE (tetrakis dimethylaminoethylene). Two exptl. methods were used: gas phase dynamics for the observation of the evolution through excited stat ...
The photoexcitation and photoionization dynamics of sodium atoms deposited on the surface of helium nanodroplets and aromatic molecules (aniline, phenol and toluene) embedded in the interior of droplets have been investigated by a variety of spectroscopic ...
Electron Beam Induced Deposition (EBID) allows deposition of three-dimensional micro- and nano-structures of conductive and insulating materials on a wide range of substrates. The process is based on the decomposition of molecules of a pre-selected precurs ...
A new method is presented for recording excitation spectra of molecules embedded in helium nanodroplets. The method relies on the complete evaporation of the droplets following excitation of an dissolved molecule and the subsequent detection of the remaini ...
An on-plate specific enrichment method is presented for the direct analysis of peptides phosphorylation. An array of sintered TiO2 nanoparticle spots was prepared on a stainless steel plate to provide porous substrate with a very large specific surface and ...
Protonation of norbom-5-en-2-one gives 6-oxo-2-norbomyl cation (2) as most stable C7H9O+ cation. Quantum calculations at B3LYP/6-31G(d) level (gas phase, 1 atm, 25 degrees C) predict a C-s-structure for 2 that can be represented as an intramolecular pi-com ...
Recent advances in peptide fragmentation techniques and mass spectrometry have opened up the possibility of combining peptide sepn. techniques, such as capillary electrophoresis (CE) and capillary liq. chromatog., with Fourier transform ion cyclotron reson ...
Mass selected cations of Ag-clusters are deposited, together with Ar seeded with CO2 (or other electron scavengers such as O2, N2O, or CCl4), on a cold substrate, while being flooded with low energy electrons. Optical absorption measurements re ...
We present in this work a new technique, which combines laser photofragmentation spectroscopy with tandem mass spectrometry, for structural investigations of biomolecular ions in the gas phase. A novel apparatus was designed and built for the implementatio ...
The formation of sub-micron sized particulates has been studied in a low pressure (0.1 mbar) radio-frequency (13.56 MHz) capacitively coupled plasma discharge. Particles are studied in situ by infrared absorption spectroscopy, laser illumination and Cavity ...